(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Base Information

Chemical Name:(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc
CAS No.:849726-33-6
Molecular Formula:C₆₄H₆₄N₄O₁₂Zn
Molecular Weight:1146.62
Hs Code.:

Synonyms:(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

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Chemical Property of (tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

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Technology Process of (tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

There total 2 articles about (tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 573658-43-2
(tetraethyl 4,4',4'',4'''-[[10-(2-[(trimethylsilyl)ethynyl]phenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

: 849726-33-6
(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; (N2); Bu4NF in THF added to a soln. of Zn complex, stirred for 15 min at20°C; H2O added, extd. (CH2Cl2), the combined org. layers dried (MgSO4), evapd. (vac.);
DOI:10.1002/hlca.200490288

Reference yield: 99.0%

: tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoate

: 5970-45-6
zinc(II) acetate dihydrate

: 849726-33-6
(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: In methanol; chloroform; (N2); Zn salt added to a soln. of ligand, stirred for 48 h at 20°C; evapd. (vac.), dissolved in CH2Cl2, the org. phase washed (H2O), dried (MgSO4), evapd. (vac.), obtained as an oil; elem. anal.;
DOI:10.1002/hlca.200490288

Reference yield: 78.0%

: 849726-33-6
(tetraethyl 4,4',4'',4'''-[[10-(2-ethynylphenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

: 10388-19-9
m-iodobenzamide

: 849726-34-7
(tetraethyl 4,4',4'',4'''-[[10-(2-[[3-(aminocarbonyl)phenyl]ethynyl]phenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In toluene; (N2); stirred for 22 h at 90°C; cooled to 20°C, satd. NaH2PO4 soln. added, the aq. layer extd. (CH2Cl2), the combined org. layers dried (MgSO4), evapd. (vac.), flash-chromd. (SiO2-H, CH2Cl2/MeOH), obtained as an oil;
DOI:10.1002/hlca.200490288