phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

Base Information

Chemical Name:phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide
CAS No.:935268-64-7
Molecular Formula:C₃₄H₂₇Cl₄NO₇S
Molecular Weight:735.469
Hs Code.:

Synonyms:phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

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Chemical Property of phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

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Technology Process of phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

There total 3 articles about phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 935268-61-4
phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside

: 935268-64-7
phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - -60 ℃; for 2h;
DOI:10.1021/ja069060g

Reference yield:

: 100-39-0
benzyl bromide

: 935268-64-7
phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: Bu₂SnO / toluene / 12 h / Heating

1.2: 51 percent / tetrabutylammonium iodide / toluene / 12 h / Heating

2.1: 91 percent / mCPBA / CH₂Cl₂ / 2 h / -78 - -60 °C

With di(n-butyl)tin oxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; toluene;
DOI:10.1021/ja069060g

Reference yield:

: 286018-83-5
phenyl 2-deoxy-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside

: 935268-64-7
phenyl 2-deoxy-3,6-di-O-benzyl-2-tetrachlorophthalimido-1-thio-β-D-glucopyranoside S-oxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: Bu₂SnO / toluene / 12 h / Heating

1.2: 51 percent / tetrabutylammonium iodide / toluene / 12 h / Heating

2.1: 91 percent / mCPBA / CH₂Cl₂ / 2 h / -78 - -60 °C

With di(n-butyl)tin oxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; toluene;
DOI:10.1021/ja069060g