2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Base Information

Chemical Name:2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile
CAS No.:115828-76-7
Molecular Formula:C₂₇H₂₉NO₆S
Molecular Weight:495.596
Hs Code.:

Synonyms:2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Suppliers and Price of 2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

There total 6 articles about 2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 124-63-0
methanesulfonyl chloride

: 115828-74-5,115828-75-6
2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-L-arabinose (E,Z)-oxime

: 115828-76-7
2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Guidance literature:: With pyridine; at 60 - 70 ℃; for 2h;
DOI:10.1021/jo00255a022

Reference yield:

: 115828-68-7
(2R,3R,4R,5R)-3,4-Bis-benzyloxy-5-ethoxy-tetrahydro-furan-2-carbaldehyde

: 115828-76-7
2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / diethyl ether / 2 h / Heating

2: 76 percent / triethylsilane, trifluoroacetic acid / CH₂Cl₂ / 48 h / Ambient temperature

3: 97 percent / 80percent acetic acid / 12 h / Heating

4: 86 percent / hydroxylamine hydrochloride, pyridine / ethanol / 5 h / Heating

5: 71 percent / pyridine / 2 h / 60 - 70 °C

With pyridine; triethylsilane; hydroxylamine hydrochloride; acetic acid; trifluoroacetic acid; In diethyl ether; ethanol; dichloromethane;
DOI:10.1021/jo00255a022

Reference yield:

: 115828-72-3,115828-73-4
2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-α,β-L-arabinose

: 115828-76-7
2,3-di-O-benzyl-5-deoxy-5-C-(4-methoxyphenyl)-4-O-(methylsulfonyl)-L-arabinonitrile

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / hydroxylamine hydrochloride, pyridine / ethanol / 5 h / Heating

2: 71 percent / pyridine / 2 h / 60 - 70 °C

With pyridine; hydroxylamine hydrochloride; In ethanol;
DOI:10.1021/jo00255a022