Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine

Base Information

• Chemical Name: Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine
• CAS No.: 148422-47-3
• Molecular Formula: C₆H₁₆N₂*C₁₃H₂₃N₂Si₂*Li
• Molecular Weight: 386.657
• Mol file: 148422-47-3.mol

Synonyms:Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine

Chemical Property of Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine

There total 1 articles about Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

N,N,N,N,-tetramethylethylenediamine (110-18-9) + benzonitrile (100-47-0) + lithium hexamethyldisilazane (4039-32-1) → (N,N'-bis(trimethylsilyl)benzamidinate)Li(N,N,N',N'-tetramethylethylenediamine) (148422-47-3)

Guidance literature:

N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane; In diethyl ether; for 1h;

benzonitrile; In diethyl ether; at 20 ℃; for 10h; Further stages.;

DOI:10.1021/ja020575r

Reference yield: 80.0%

trans-Cl2V(N,N,N',N'-tetramethylethylenediamine)2 (122116-24-9,161816-44-0) + (N,N'-bis(trimethylsilyl)benzamidinate)Li(N,N,N',N'-tetramethylethylenediamine) (148422-47-3) → V(Si(CH3)3NC(C6H5)NSi(CH3)3)2(C4H8O)2 (157443-07-7)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring at room temp. for 3 h, boiling to dissoln.; crystn. on slow cooling to room temp. and standing overnight; elem. anal.;

DOI:10.1016/0020-1693(95)04757-3

Reference yield: 78.1%

Li[PhC(N(trimethylsilane))2]N,N,N',N'-tetramethylethylenediamine (148422-47-3) + [ThCl4(1,2-dimethoxyethane)2] (639084-65-4) → Th(N,N′-bis(trimethylsilyl)benzamidinate)2Cl(μ-Cl)2Li(tetramethylethylenediamine)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c9dt00811j

upstream raw materials:

N,N,N,N,-tetramethylethylenediamine

benzonitrile

lithium hexamethyldisilazane

Downstream raw materials:

{Ph-C(NSiMe₃)2}2ZrCl₂

V(Si(CH₃)3NC(C₆H₅)NSi(CH₃)3)2(C₄H₈O)2

[C₆H₅C(NSi(CH₃)3)2]2TaF₃

V((CH₃)3SiNC(C₆H₅)NSi(CH₃)3)((CH₃)2NCH₂CH₂N(CH₃)2)Cl₂

Refernces