5,12-dichloro-6,11-diphenyltetracene

Base Information

• Chemical Name: 5,12-dichloro-6,11-diphenyltetracene
• CAS No.: 60104-31-6
• Molecular Formula: C₃₀H₁₈Cl₂
• Molecular Weight: 449.379
• Mol file: 60104-31-6.mol

Synonyms:5,12-dichloro-6,11-diphenyltetracene

Chemical Property of 5,12-dichloro-6,11-diphenyltetracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,12-dichloro-6,11-diphenyltetracene

There total 2 articles about 5,12-dichloro-6,11-diphenyltetracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

6,11-dichloro-5,12-naphthacenequinone (73693-15-9) + phenyllithium (591-51-5) → 5,12-dichloro-6,11-diphenyltetracene (60104-31-6)

Guidance literature:

6,11-dichloro-5,12-naphthacenequinone; phenyllithium; In tetrahydrofuran; at -78 - 20 ℃;

With hydrogenchloride; tin(ll) chloride; In tetrahydrofuran; water; at 20 ℃; for 1h;

DOI:10.1021/ol300098p

Reference yield:

6,11-dichloro-5,12-diphenyl-5,12-dihydro-naphthacene-5,12-diol (858455-58-0) → 5,12-dichloro-6,11-diphenyltetracene (60104-31-6)

Guidance literature:

With titanium(III) chloride;

Reference yield: 44.0%

5,12-dichloro-6,11-diphenyltetracene (60104-31-6) + phenylmagnesium bromide (100-58-3) → 9,10-diphenylindeno[1,2,3-fg]tetracene (124537-32-2)

Guidance literature:

With C₃₂H₄₀BrCl₂N₃Pd; In 1,4-dioxane; diethyl ether; at 70 ℃; for 24h; chemoselective reaction; Inert atmosphere;

DOI:10.1021/ol300098p

upstream raw materials:

6,11-dichloro-5,12-diphenyl-5,12-dihydro-naphthacene-5,12-diol

6,11-dichloro-5,12-naphthacenequinone

phenyllithium

Downstream raw materials:

5,12-dichloro-6,11-diphenyl-5,12-dihydro-5,12-epidioxido-naphthacene

6,11-diphenylnaphthacene

5,6:11,12-di-o-phenylene-tetracene

9-chloro-10-phenylindeno[1,2,3-fg]tetracene

Refernces