124537-32-2Relevant articles and documents
Domino Cross-Scholl Reaction of Tetracene with Molecular Benzene: Synthesis, Structure, and Mechanism
Harada, Ai,Kishimoto, Yusho,Mishima, Daisuke,Muraoka, Masahiro,Murata, Michihisa,Nakanishi, Haruka,Togo, Masahiro,Tsuboi, Yui,Yamada, Yuto,Yamanaka, Yohei
supporting information, p. 7921 - 7926 (2021/10/12)
A domino-type multiple C-H functionalization of tetracene with molecular benzene is reported. Under the typical conditions of the Scholl reaction, a domino reaction occurs between tetracene and six molecules of benzene in one pot to furnish an aromatic compound with a curved π-system. This reaction sequence involves oxidative cross-dehydrogenative coupling/annulation and Friedel-Crafts-type reactions. Eight C-C bonds are formed via this intermolecular domino reaction without mediation by a metal or the assistance of a specific substituent.
Diarylindenotetracenes via a selective cross-coupling/C-H functionalization: Electron donors for organic photovoltaic cells
Gu, Xingxian,Luhman, Wade A.,Yagodkin, Elisey,Holmes, Russell J.,Douglas, Christopher J.
supporting information; experimental part, p. 1390 - 1393 (2012/05/04)
A direct synthesis of new donor materials for organic photovoltaic cells is reported. Diaryindenotetracenes were synthesized utilizing a Kumada-Tamao-Corriu cross-coupling of peri-substituted tetrachlorotetracene with spontaneous indene annulation via C-H