Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

Base Information

Chemical Name:Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester
CAS No.:177949-21-2
Molecular Formula:C₁₃H₁₅ClO₄
Molecular Weight:270.713
Hs Code.:

Synonyms:Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

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Chemical Property of Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

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Technology Process of Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

There total 5 articles about Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 144071-99-8
1-methyl-5-O-benzoyl-2-deoxy-α-D-ribofuranoside

: 177949-21-2
Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

Guidance literature:: With thionyl chloride; In N,N,N,N,N,N-hexamethylphosphoric triamide; 1.) 0 deg C, 10 min, 2.) room temperature, 6 h;
DOI:10.1135/cccc19960478

Reference yield:

: 98-88-4
benzoyl chloride

: 177949-21-2
Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / pyridine / 0.5 h / 0 °C

2: CrO₃, Ac₂O / pyridine / 1.) 0 deg C, 10 min, 2.) room temperature, 10 min

3: NaBH₄ / ethanol / 0.33 h / 0 °C

4: 76 percent / SOCl₂ / hexamethylphosphoric acid triamide / 1.) 0 deg C, 10 min, 2.) room temperature, 6 h

With pyridine; chromium(VI) oxide; sodium tetrahydroborate; thionyl chloride; acetic anhydride; In pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol;
DOI:10.1135/cccc19960478

Reference yield:

: 1-O-methyl-2-deoxy-5-O-benzoyl-αβ-D-furan-3-ulose

: 177949-21-2
Benzoic acid (2R,3R,5S)-3-chloro-5-methoxy-tetrahydro-furan-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄ / ethanol / 0.33 h / 0 °C

2: 76 percent / SOCl₂ / hexamethylphosphoric acid triamide / 1.) 0 deg C, 10 min, 2.) room temperature, 6 h

With sodium tetrahydroborate; thionyl chloride; In N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol;
DOI:10.1135/cccc19960478