1-phenyl-9-(pyridin-2-yl)-9H-carbazole

Base Information

• Chemical Name: 1-phenyl-9-(pyridin-2-yl)-9H-carbazole
• CAS No.: 1416353-37-1
• Molecular Formula: C₂₃H₁₆N₂
• Molecular Weight: 320.393
• Mol file: 1416353-37-1.mol

Synonyms:1-phenyl-9-(pyridin-2-yl)-9H-carbazole

Chemical Property of 1-phenyl-9-(pyridin-2-yl)-9H-carbazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenyl-9-(pyridin-2-yl)-9H-carbazole

There total 16 articles about 1-phenyl-9-(pyridin-2-yl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

9-(2-pyridyl)carbazole (23866-67-3) + phenylboronic acid (98-80-6) → 1-phenyl-9-(pyridin-2-yl)-9H-carbazole (1416353-37-1)

Guidance literature:

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; bis-[(trifluoroacetoxy)iodo]benzene; In toluene; at 100 ℃; for 3h; Sealed tube;

DOI:10.1039/c5ra18402a

Reference yield:

C38H28N4O4Pd2 (1416353-77-9) + potassium phenyltrifluoborate → 1-phenyl-9-(pyridin-2-yl)-9H-carbazole (1416353-37-1) + 1,8-diphenyl-9-(pyridin-2-yl)-9H-carbazole (1416353-38-2)

Guidance literature:

With p-benzoquinone; In tert-butyl alcohol; at 60 - 70 ℃; for 4h; Reagent/catalyst; Overall yield = 75 %Chromat.;

DOI:10.1021/om301071m

Reference yield:

2-iodopyridine (5029-67-4) → 1-phenyl-9-(pyridin-2-yl)-9H-carbazole (1416353-37-1)

Guidance literature:

Multi-step reaction with 2 steps

1: copper; potassium carbonate / N,N-dimethyl-formamide / 30 h / 130 - 140 °C

2: palladium diacetate; p-benzoquinone; silver nitrate / dichloromethane / 24 h / 60 - 70 °C

With palladium diacetate; copper; potassium carbonate; silver nitrate; p-benzoquinone; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/om301071m

upstream raw materials:

2-iodopyridine

9H-carbazole

C₃₈H₂₈N₄O₄Pd₂

9-(2-pyridyl)carbazole

Downstream raw materials:

1-phenyl-9H-carbazole