4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

Base Information

Chemical Name:4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester
CAS No.:869964-21-6
Molecular Formula:C₂₃H₄₀O₅Si₂
Molecular Weight:452.739
Hs Code.:

Synonyms:4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

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Chemical Property of 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

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Technology Process of 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

There total 12 articles about 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 869964-34-1
4,6-bis-tert-butyldimethylsilanyloxy-2-methoxycarbonylmethyl-3-methylbenzoic acid methyl ester

: 869964-21-6
4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; Inert atmosphere;
DOI:10.1021/ja207331m

Reference yield: 64.0%

: C₂₄H₄₂O₄Si₂

: 869964-21-6
4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

Guidance literature:: With 2,6-dimethylpyridine; potassium osmate(VI) dihydrate; sodium periodate; In 1,4-dioxane; water; at 20 ℃; for 5h;
DOI:10.1002/chem.201203149

Reference yield:

: 292157-65-4
4,6-dihydroxy-2-methoxycarbonylmethyl-3-methylbenzoic acid methyl ester

: 869964-21-6
4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / 2,6-lutidine / CH₂Cl₂ / 6 h / 20 °C

2: di-iso-butylaluminum hydride / CH₂Cl₂; hexane / 2 h / -78 °C

With 2,6-dimethylpyridine; diisobutylaluminum hydride; In hexane; dichloromethane;
DOI:10.1021/ol0520267