C₁₉H₃₄O₂SSi

Base Information

Chemical Name:C₁₉H₃₄O₂SSi
CAS No.:1422375-08-3
Molecular Formula:C₁₉H₃₄O₂SSi
Molecular Weight:354.629
Hs Code.:

C<sub>19</sub>H<sub>34</sub>O<sub>2</sub>SSi

Synonyms:C₁₉H₃₄O₂SSi

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Chemical Property of C₁₉H₃₄O₂SSi

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Technology Process of C₁₉H₃₄O₂SSi

There total 5 articles about C₁₉H₃₄O₂SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 882-33-7
diphenyldisulfane

: (2R,3S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-isopropyl-butane-1,3-diol

: 1422375-08-3
C₁₉H₃₄O₂SSi

Guidance literature:: With pyridine; tributylphosphine; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol400157s

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1422375-08-3
C₁₉H₃₄O₂SSi

Guidance literature:: Multi-step reaction with 5 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 2 h / -30 °C / Inert atmosphere

2.1: diethyl (2R,3R)-tartrate; titanium(IV)isopropoxide / dichloromethane / 0.33 h / -25 °C / Inert atmosphere

2.2: 63 h / -25 °C / Inert atmosphere

3.1: copper(I) bromide dimethylsulfide complex / diethyl ether; tetrahydrofuran / 0.17 h / -50 - -20 °C / Inert atmosphere

3.2: 21 h / -20 °C / Inert atmosphere

3.3: Inert atmosphere

4.1: tris(triphenylphosphine)rhodium(l) chloride; hydrogen / benzene; ethanol / 5 h / 20 °C / Inert atmosphere

5.1: pyridine; tributylphosphine / 1 h / 20 °C / Inert atmosphere

With pyridine; 1H-imidazole; tris(triphenylphosphine)rhodium(l) chloride; copper(I) bromide dimethylsulfide complex; diethyl (2R,3R)-tartrate; tributylphosphine; hydrogen; titanium(IV)isopropoxide; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; benzene; 2.1: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/ol400157s

Reference yield:

: (2R,3S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-isopropenyl-butane-1,3-diol

: 1422375-08-3
C₁₉H₃₄O₂SSi

Guidance literature:: Multi-step reaction with 2 steps

1: tris(triphenylphosphine)rhodium(l) chloride; hydrogen / benzene; ethanol / 5 h / 20 °C / Inert atmosphere

2: pyridine; tributylphosphine / 1 h / 20 °C / Inert atmosphere

With pyridine; tris(triphenylphosphine)rhodium(l) chloride; tributylphosphine; hydrogen; In ethanol; benzene;
DOI:10.1021/ol400157s