1-(1-phenylvinyl)cyclopropanol

Base Information

Chemical Name:1-(1-phenylvinyl)cyclopropanol
CAS No.:68423-18-7
Molecular Formula:C₁₁H₁₂O
Molecular Weight:160.216
Hs Code.:

Synonyms:1-(1-phenylvinyl)cyclopropanol

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Chemical Property of 1-(1-phenylvinyl)cyclopropanol

Chemical Property:

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Technology Process of 1-(1-phenylvinyl)cyclopropanol

There total 4 articles about 1-(1-phenylvinyl)cyclopropanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 98-81-7
1-bromovinylbenzene

: 29526-99-6
1-methylcyclopropanol

: 68423-18-7
1-(1-phenylvinyl)cyclopropanol

Guidance literature:: 1-bromovinylbenzene; With iodine; magnesium; ethylene dibromide; In tetrahydrofuran; at 60 ℃; for 1h; Inert atmosphere;

1-methylcyclopropanol; In tetrahydrofuran; diethyl ether; at 0 - 60 ℃; for 5h;
DOI:10.1021/ja500716j

Reference yield:

: 98-81-7
1-bromovinylbenzene

: 5009-27-8
cyclopropanone

: 68423-18-7
1-(1-phenylvinyl)cyclopropanol

Guidance literature:: 1-bromovinylbenzene; With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

cyclopropanone; In tetrahydrofuran; hexane; at 25 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/acs.orglett.8b01627

Reference yield:

: 98-86-2
acetophenone

: 68423-18-7
1-(1-phenylvinyl)cyclopropanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: triphenyl phosphite; bromine; triethylamine / dichloromethane / -78 - 25 °C / Inert atmosphere

2.1: tert.-butyl lithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 0.5 h / 25 °C / Inert atmosphere

With triphenyl phosphite; bromine; tert.-butyl lithium; triethylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/acs.orglett.8b01627