dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

Base Information

Chemical Name:dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
CAS No.:112792-45-7
Molecular Formula:C₂₄H₄₃CoO₂P₂S
Molecular Weight:516.611
Hs Code.:

Synonyms:dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

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Chemical Property of dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

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Technology Process of dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

There total 2 articles about dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 6591-06-6
diethylphosphine sulfide

: 112792-41-3
ICo(CO)2(P(C₆H₁₁)3)2

: 7087-68-5
N-ethyl-N,N-diisopropylamine

: N,N-diisopropylethylamine hydroiodide

: 112792-45-7
dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

: 2622-14-2
tricyclohexylphosphine

Guidance literature:: In toluene; under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C2H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;

Reference yield:

: 112792-60-6
tricarbonyl(diethylthiophosphinito-P)(tricyclohexylphosphane)cobalt(I)

: 112792-45-7
dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

Guidance literature:: In not given; byproducts: CO; 40-50°C, stream of inert gas (N2);

Reference yield: 67.0%

: 112792-45-7
dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

: 112792-60-6
tricarbonyl(diethylthiophosphinito-P)(tricyclohexylphosphane)cobalt(I)

Guidance literature:: With CO; In hexane; under N2 or Ar, exclusion of oxygen and moisture, stirred 5 h under CO (1.06 bar) at 25°C; filtration of pptn. under CO, dried in a CO-stream and then in vac.; elem. anal.;