(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

Base Information

Chemical Name:(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene
CAS No.:152125-18-3
Molecular Formula:C₂₄H₃₈O₃SSi
Molecular Weight:434.715
Hs Code.:

Synonyms:(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

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Chemical Property of (E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

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Technology Process of (E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

There total 7 articles about (E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 152125-17-2
(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

: 873-55-2
sodium benzenesulfonate

: 152125-18-3
(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol;

Reference yield:

: 20548-02-1
trans (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexanone

: 152125-18-3
(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / Et₃N, 4-dimethylaminopyridine / CH₂Cl₂ / 2 h / Ambient temperature

2: 1) iPr₂NLi / 1) THF, hexane, 1 h, -78 deg C, 2) THF, 5 h, 0 deg C

3: 93 percent / Et₃N / PdCl₂(Ph₃P)2 / dimethylformamide / 22 h / 75 °C

4: LiAlH₄ / diethyl ether / 0.5 h / 0 °C

5: pyridine / 16 h / Ambient temperature

6: 89 percent / Pd(Ph₃P)4 / tetrahydrofuran; methanol / 1 h / Ambient temperature

With pyridine; dmap; lithium aluminium tetrahydride; triethylamine; lithium diisopropyl amide; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 83021-09-4
(E)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-prop-2-en-1-ol

: 152125-18-3
(E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 16 h / Ambient temperature

2: 89 percent / Pd(Ph₃P)4 / tetrahydrofuran; methanol / 1 h / Ambient temperature

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol;