((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

Base Information

Chemical Name:((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol
CAS No.:133661-21-9
Molecular Formula:C₁₇H₂₆O₃
Molecular Weight:278.392
Hs Code.:

Synonyms:((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

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Chemical Property of ((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

Chemical Property:

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Technology Process of ((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

There total 7 articles about ((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 133661-20-8,151433-57-7
(1RS,2SR,4RS,6SR)-dimethyl-4-benzyloxy-1,6-dimethylcyclohexane-1,2-dicarboxylate

: 133661-21-9
((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at 20 ℃; Yield given;
DOI:10.1016/S0040-4039(00)74881-7

Reference yield:

: 133661-15-1
4,5-dimethyl-3-cyclohexen-1-one

: 133661-21-9
((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

Guidance literature:: Multi-step reaction with 5 steps

1: LS-Selectride / tetrahydrofuran / -100 °C

2: 98 percent / NaH; N-Bu₄NI / tetrahydrofuran / 2 h / Heating

3: POCl₃; Zn-Cu / diethyl ether / 16 h / 20 °C

4: LiAlH₄ / tetrahydrofuran / 12 h / 20 °C

With lithium aluminium tetrahydride; tetra-(n-butyl)ammonium iodide; copper; sodium hydride; lithium tri-sec-butyl(hydrido)borate; zinc; trichlorophosphate; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ja0208456

Reference yield:

: 133661-18-4
(1R,2S,4R,6S)-4-Benzyloxy-8,8-dichloro-1,2-dimethyl-bicyclo[4.2.0]octan-7-one

: 133661-21-9
((1R,2S,4R,6S)-4-Benzyloxy-2-hydroxymethyl-1,6-dimethyl-cyclohexyl)-methanol

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / tetrahydrofuran / 12 h / 20 °C

With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1021/ja0208456