(C₉H₇)PdCl(P(C₆H₅)3)

Base Information

• Chemical Name: (C₉H₇)PdCl(P(C₆H₅)3)
• CAS No.: 677029-42-4
• Molecular Formula: C₂₇H₂₂ClPPd
• Molecular Weight: 519.318
• Mol file: 677029-42-4.mol

Synonyms:(C₉H₇)PdCl(P(C₆H₅)3)

Chemical Property of (C₉H₇)PdCl(P(C₆H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₉H₇)PdCl(P(C₆H₅)3)

There total 2 articles about (C₉H₇)PdCl(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

bis(μ-chloro)bis(η3-indenyl)dipalladium(II) (90624-27-4) + triphenylphosphine (603-35-0) → [(η5-indenyl)Pd(II)(Cl)(PPh3)] (677029-42-4)

Guidance literature:

In diethyl ether; under inert atm.; PPh3 was added to stirred suspn. of Pd complex at roomtemp., stirring for 1 h; soln. was concd., ppt. was filtered off; elem. anal.;

DOI:10.1021/om034253n

Reference yield: 60.0%

cis-dichlorobis(benzonitrile)palladium(II) (14220-64-5,15617-18-2,39958-10-6) + lithium indenide (20669-47-0) + triphenylphosphine (603-35-0) → [(η5-indenyl)Pd(II)(Cl)(PPh3)] (677029-42-4)

Guidance literature:

In diethyl ether; under inert atm.; soln. of indenyl was added to stirred suspn. of Pd complex at -78°C, mixt. was warmed to room temp., stirred for 30 min, PPh3 was added, mixt. stirred for 30 min; mixt. was filtered, filtrate was concd., ppt. was filtered off; elem. anal.;

DOI:10.1021/om034253n

Reference yield: 87.0%

silver tetrafluoroborate (14104-20-2) + [(η5-indenyl)Pd(II)(Cl)(PPh3)] (677029-42-4) + triphenylphosphine (603-35-0) → (C9H7)Pd(P(C6H5)3)2(1+)*BF4(1-)=(C9H7)Pd(P(C6H5)3)2BF4 (875647-35-1)

Guidance literature:

In dichloromethane; byproducts: AgCl; (N2 atm., Schlenk) a mixt. of complex, AgBF4 and P(C6H5)3 was stirred inCH2Cl2 for 1.5 h at room temp.; filtered, concd., diethyl ether was added, ppt. was filtered, recrystd. from cold CH2Cl2/diethyl ether; elem. anal.;

DOI:10.1021/om050826f

upstream raw materials:

cis-dichlorobis(benzonitrile)palladium(II)

lithium indenide

triphenylphosphine

bis(μ-chloro)bis(η3-indenyl)dipalladium(II)

Downstream raw materials:

(C₉H₇)Pd(P(C₆H₅)3)(CF₃SO₃)

(C₉H₆CH₃)Pd(P(C₆H₅)3)(CF₃SO₃)

(C₉H₇)Pd(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=(C₉H₇)Pd(P(C₆H₅)3)2BF₄

(C₆H₅CH₂NH₂)(P(C₆H₅)3)PdCl₂