(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

Base Information

Chemical Name:(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane
CAS No.:1203571-49-6
Molecular Formula:C₂₆H₃₆OSi
Molecular Weight:393.649
Hs Code.:

(E)-[6-<sup>2</sup>H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

Synonyms:(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

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Chemical Property of (E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

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Technology Process of (E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

There total 10 articles about (E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: (E)-[1,1-2H₂]-{6-[(tert-butyldiphenylsilyl)oxy]-4-methylhex-4-en-1-yl}triphenylphosphonium iodide

: 67-64-1
acetone

: 1203571-49-6
(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

Guidance literature:: (E)-[1,1-2H₂]-{6-[(tert-butyldiphenylsilyl)oxy]-4-methylhex-4-en-1-yl}triphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 1.5h;

acetone; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1002/ejoc.201403002

Reference yield: 71.0%

: 1203571-48-5
1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal

: 24470-78-8
isopropyltriphenylphosphonium iodide

: 1203571-49-6
(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

Guidance literature:: isopropyltriphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.666667h; Inert atmosphere;

1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal; In tetrahydrofuran; hexane; for 0.166667h; Inert atmosphere;
DOI:10.1002/chem.200901563

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1203571-49-6
(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane

Guidance literature:: Multi-step reaction with 9 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 0 - 20 °C

2.1: 3-chloro-benzenecarboperoxoic acid / chloroform / 1 h / 0 °C

3.1: tetrahydrofuran / 1.5 h / 0 °C

3.2: 2 h / 0 °C

4.1: potassium hydroxide; iodine / 1.5 h / 0 °C

5.1: lithium aluminium deuteride / tetrahydrofuran / 2 h / 0 °C

6.1: pyridine / 3 h / 0 °C

7.1: sodium iodide / acetone / 20 °C

8.1: toluene / 3 h / Reflux

9.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / 0 °C

9.2: -78 - 20 °C

With pyridine; 1H-imidazole; n-butyllithium; lithium aluminium deuteride; iodine; 3-chloro-benzenecarboperoxoic acid; sodium iodide; potassium hydroxide; In tetrahydrofuran; hexane; chloroform; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1002/ejoc.201403002