[HC_.tplbond.CCH₂Ph][Co₂(CO)6]

Base Information

Chemical Name:[HC_.tplbond.CCH₂Ph][Co₂(CO)6]
CAS No.:201985-09-3
Molecular Formula:C₁₅H₈Co₂O₆
Molecular Weight:402.211
Hs Code.:

[HC<sub>.</sub>tplbond.CCH<sub>2</sub>Ph][Co<sub>2</sub>(CO)6]

Synonyms:[HC_.tplbond.CCH₂Ph][Co₂(CO)6]

Suppliers and Price of [HC_.tplbond.CCH₂Ph][Co₂(CO)6]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [HC_.tplbond.CCH₂Ph][Co₂(CO)6]

Chemical Property:

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Technology Process of [HC_.tplbond.CCH₂Ph][Co₂(CO)6]

There total 4 articles about [HC_.tplbond.CCH₂Ph][Co₂(CO)6] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 728946-56-3,198139-01-4
(μ-η2-3-methoxy-3-phenyl-1-propyne)dicobalt hexacarbonyl

: 201985-09-3
[HC_.tplbond.CCH₂Ph][Co₂(CO)6]

: 231609-28-2
(3,4-diphenyl-1,5-hexadiyne)dicobalt hexacarbonyl

: 154975-41-4,154975-40-3,78724-79-5
μ-η(2)-(3,4-diphenyl-1,5-hexadiyne)-bis-dicobalt hexacarbonyl

Guidance literature:: With trifluoromethylsulfonic anhydride; In 1,2-dichloro-ethane; (N2); Schlenk technique; anhydride added dropwise to Co complex/C2H4Cl2 (-20°C); stirred (-20°C, 10 min; 20°C, 10 min); re fluxed (83°C, 3 min); cooled (20°C); MeOH added; stirred (30 min); Co2(CO)8 added; stirred (2 h; dild. with H2O; extd. (ether); org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); fractionally chromd. (silica gel plate, petroleum ether/CH2Cl2, 10/1);
DOI:10.1021/om900448j

Reference yield: 61.9%

: 728946-56-3,198139-01-4
(μ-η2-3-methoxy-3-phenyl-1-propyne)dicobalt hexacarbonyl

: 201985-09-3
[HC_.tplbond.CCH₂Ph][Co₂(CO)6]

: 154975-41-4,154975-40-3,78724-79-5
μ-η(2)-(3,4-diphenyl-1,5-hexadiyne)-bis-dicobalt hexacarbonyl

Guidance literature:: With Tf₂O; Cp₂Co; In dichloromethane; (N2) Tf2O was added dropwise to soln. Co complex in CH2Cl2 at -50°C, react. mixt. was brought to -10°C for 30 min, soln. Cp2Co in CH2Cl2 was added dropwise at -50°C, stirred for 10 min; react. mixt was diluted with brine, warmed to 0°C in 40 min, extd. with ether, washed with water, dried over Na2SO4, solvent was removed in vacuo, prep. TLC - mixt. of diastereomers;
DOI:10.1021/om2006497

Reference yield:

: 100-52-7
benzaldehyde

: 201985-09-3
[HC_.tplbond.CCH₂Ph][Co₂(CO)6]

: 154975-41-4,154975-40-3,78724-79-5
μ-η(2)-(3,4-diphenyl-1,5-hexadiyne)-bis-dicobalt hexacarbonyl

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: Tf₂O; Cp₂Co / dichloromethane

With Tf₂O; Cp₂Co; In diethyl ether; dichloromethane;
DOI:10.1021/om2006497