4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane

Base Information

Chemical Name:4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane
CAS No.:603143-27-7
Molecular Formula:C13H19BO4S
Molecular Weight:282.168
Hs Code.:2934999090
European Community (EC) Number:675-103-2
DSSTox Substance ID:DTXSID30374822
Wikidata:Q72488924
Mol file:603143-27-7.mol

Synonyms:603143-27-7;4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane;2-(4-Methanesulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4-(Methanesulfonyl)phenylboronic acid pinacol ester;4,4,5,5-tetramethyl-2-(4-methylsulfonylphenyl)-1,3,2-dioxaborolane;4-(methanesulfonyl)phenylboronic acid, pinacol ester;4-methylsulfonylphenylboronic acid, pinacol ester;2-(4-methanesulfonylphenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane;4,4,5,5-tetramethyl-2-[4-(methylsulfonyl)phenyl]-1,3,2-dioxaborolane;n-methyliodofluoroacetamide;4-Methylsulfonylphenylboronic acid pinacol ester;SCHEMBL10904;DTXSID30374822;BDOSWBBKOSGKAV-UHFFFAOYSA-N;CS-M1424;MFCD05863921;AKOS015960086;AB22736;AS-2743;FT-0742804;4-Methylsulfonylphenylboronic acid,pinacol ester;EN300-213844;A832688;Z1741964481;2-(4-methanesulfonyl-phenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane;2-[4-(Methanesulfonyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4,4,5,5-tetra methyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane;4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)-phenyl)-1,3,2-dioxaborolane;2-(4-methanesulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, AldrichCPR

Suppliers and Price of 4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-(4-Methanesulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
10mg
$ 45.00

SynQuest Laboratories
2-(4-Methanesulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
5 g
$ 288.00

Matrix Scientific
4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)-phenyl)-1,3,2-dioxaborolane 95+%
5g
$ 415.00

Matrix Scientific
4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)-phenyl)-1,3,2-dioxaborolane 95+%
1g
$ 184.00

Crysdot
4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane 95+%
5g
$ 248.00

ChemScene
4,4,5,5-tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane
1g
$ 63.00

Chemenu
4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane 95%+
1000g
$ 3128.00

AOBChem
4-(Methanesulfonyl)phenylboronicacid,pinacolester 97%
100g
$ 1304.00

American Custom Chemicals Corporation
4-(METHANESULFONYL)PHENYLBORONIC ACID, PINACOL ESTER 95.00%
5G
$ 1291.58

American Custom Chemicals Corporation
4-(METHANESULFONYL)PHENYLBORONIC ACID, PINACOL ESTER 95.00%
1G
$ 719.17

Total 31 raw suppliers

Chemical Property of 4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane

Chemical Property:

Vapor Pressure:6.53E-07mmHg at 25°C
Melting Point:162-163°C
Refractive Index:1.517
Boiling Point:421.1 °C at 760 mmHg
Flash Point:208.5 °C
PSA：60.98000
Density:1.17g/cm³
LogP:2.47010
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:282.1097104
Heavy Atom Count:19
Complexity:414

Purity/Quality:

97% ^*data from raw suppliers

2-(4-Methanesulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC=C(C=C2)S(=O)(=O)C

Technology Process of 4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane

There total 12 articles about 4,4,5,5-Tetramethyl-2-(4-(methylsulfonyl)phenyl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 190788-58-0
4,4,5,5-tetramethyl-2-(4-methylsulfanylphenyl)-[1,3,2]-dioxaborolane

: 603143-27-7
(4,4,5,5-tetramethyl-2-[4-(methylsulfonyl)phenyl])-1,3,2-dioxaborolane

Guidance literature:: With dihydrogen peroxide; In N,N-dimethyl-formamide; acetonitrile; at 40 ℃; for 1h;
DOI:10.1002/adma.201906437

Reference yield: 90.0%

: 1,3-dioxoisoindolin-2-yl 4-(methylsulfonyl)benzoate

: 73183-34-3
bis(pinacol)diborane

: 603143-27-7
(4,4,5,5-tetramethyl-2-[4-(methylsulfonyl)phenyl])-1,3,2-dioxaborolane

Guidance literature:: With isonicotinate tert-butyl ester; at 110 ℃; for 24h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.7b01950

Reference yield: 89.0%

: 98-57-7
4-chlorophenyl methyl sulfone

: 73183-34-3
bis(pinacol)diborane

: 603143-27-7
(4,4,5,5-tetramethyl-2-[4-(methylsulfonyl)phenyl])-1,3,2-dioxaborolane

Guidance literature:: With C₂₄H₃₉O₂P*BF₄^(1-)*H⁽¹⁺⁾; potassium acetate; palladium diacetate; In 1,4-dioxane; at 110 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c4ob00293h