(+)-Pinaneborane

Base Information

Chemical Name:(+)-Pinaneborane
CAS No.:90084-43-8
Molecular Formula:C10H17 B O2
Molecular Weight:180.05
Hs Code.:
Mol file:90084-43-8.mol

Synonyms:4,6-Methano-1,3,2-benzodioxaborole,hexahydro-3a,5,5-trimethyl-, (3aS,4R,6R,7aR)- (9CI);4,6-Methano-1,3,2-benzodioxaborole, hexahydro-3a,5,5-trimethyl-, [3aS-(3aa,4b,6b,7aa)]-

Suppliers and Price of (+)-Pinaneborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(+)-PinanediolBorane
2.5g
$ 265.00

TRC
(+)-PinanediolBorane
1g
$ 120.00

American Custom Chemicals Corporation
(+)-PINANEBORANE 95.00%
1KG
$ 29452.50

Total 20 raw suppliers

Chemical Property of (+)-Pinaneborane

Chemical Property:

PSA：18.46000
LogP:1.49300
Storage Temp.:Refrigerated.
Solubility.:Chloroform (Slightly), Toluene (Sparingly)

Purity/Quality:

97% ^*data from raw suppliers

(+)-PinanediolBorane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses (+)-Pinanediol Borane is a chiral catalyst used in the synthesis of N-acyl L-amino acids.

Technology Process of (+)-Pinaneborane

There total 2 articles about (+)-Pinaneborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 18680-27-8
pinanediol

: 13292-87-0
dimethyl sulfide borane

: 90084-43-8
(3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: In tetrahydrofuran; A soln. of reagents in THF was stirred under Ar at 0°C, then at 20-25°C for 2 H;; distilled; elem. anal.;;

Reference yield:

: 18680-27-8
pinanediol

: 90084-43-8
(3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: With dimethylsulfide borane complex; In 1,4-dioxane;

Reference yield: 97.0%

: 1-(tert-butyl) 2-methyl (2R,3R,Z)-3-allyl-4-(2-(benzyloxy)-2-oxoethylidene)pyrrolidine-1,2-dicarboxylate

: 90084-43-8
(3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

: 1-(tert-butyl) 2-methyl (2R,3R,Z)-4-(2-(benzyloxy)-2-oxoethylidene)-3-(3-((3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborol-2-yl)propyl)pyrrolidine-1,2-dicarboxylate

Guidance literature:: (3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole; With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1,2-bis-(diphenylphosphino)ethane; In dichloromethane; at 25 ℃; for 0.333333h; Inert atmosphere;

1-(tert-butyl) 2-methyl (2R,3R,Z)-3-allyl-4-(2-(benzyloxy)-2-oxoethylidene)pyrrolidine-1,2-dicarboxylate; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/acsmedchemlett.1c00258