N-Morpholinium trifluoromethanesulfonate

Base Information

• Chemical Name: N-Morpholinium trifluoromethanesulfonate
• CAS No.: 77534-70-4
• Molecular Formula: CHF₃O₃S*C₄H₉NO
• Molecular Weight: 237.2
• Hs Code.: 2934999090
• DSSTox Substance ID: DTXSID30380983
• Mol file: 77534-70-4.mol

Synonyms:77534-70-4;N-Morpholinium trifluoromethanesulfonate;morpholinium trifluoromethanesulfonate;morpholin-4-ium;trifluoromethanesulfonate;SCHEMBL14975986;DTXSID30380983;MFCD03094347;morpholinium trifluoromethanesulphonate;AKOS015853130;Morpholin-4-ium trifluoromethanesulfonate;FT-0676858;A839129;1-oxa-4-azanyliacyclohexane

Chemical Property of N-Morpholinium trifluoromethanesulfonate

Chemical Property:

• Vapor Pressure: 1.14mmHg at 25°C
• Boiling Point: 162°C at 760 mmHg
• PSA: 84.01000
• LogP: 1.40980
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 237.02826346
• Heavy Atom Count: 14
• Complexity: 179

Purity/Quality:

98%min ^*data from raw suppliers

N-MorpholiniumTrifluoromethanesulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COCC[NH2+]1.C(F)(F)(F)S(=O)(=O)[O-]

Technology Process of N-Morpholinium trifluoromethanesulfonate

There total 2 articles about N-Morpholinium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

morpholine (110-91-8,99108-56-2) + trifluoromethylsulfonic anhydride (358-23-6) → 1-(trifluoromethanesulfonyl)morpholine + morpholinium trifluoromethanesulfonate (77534-70-4)

Guidance literature:

In dichloromethane; at 20 ℃; for 24h;

DOI:10.1023/B:RUJO.0000010190.79187.b9

Reference yield:

morpholine (110-91-8,99108-56-2) + N,N-phenylbistrifluoromethane-sulfonimide (37595-74-7) → phenyl trifluoromethanesulfonamide (456-64-4) + 1-(trifluoromethanesulfonyl)morpholine + morpholinium trifluoromethanesulfonate (77534-70-4)

Guidance literature:

In dichloromethane; at 20 ℃; Title compound not separated from byproducts;

DOI:10.1023/B:RUJO.0000010190.79187.b9

upstream raw materials:

morpholine

N,N-phenylbistrifluoromethane-sulfonimide

trifluoromethylsulfonic anhydride

Refernces