(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

Base Information

Chemical Name:(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate
CAS No.:1360054-11-0
Molecular Formula:C₁₃H₁₃BrCl₃NO₂
Molecular Weight:401.515
Hs Code.:

Synonyms:(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

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Technology Process of (E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

There total 4 articles about (E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1360054-35-8
(E)-4-bromo-2-(5-hydroxypent-3-enyl)phenol

: 545-06-2
trichloroacetonitrile

: 1360054-11-0
(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo202553a

Reference yield:

: 20921-00-0
6-bromo-3,4-dihydro-2H-1-benzopyran-2-one

: 1360054-11-0
(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

Guidance literature:: Multi-step reaction with 4 steps

1.1: diisobutylaluminium hydride / toluene / -78 - 0 °C / Inert atmosphere

1.2: 1 h / 20 °C / Inert atmosphere

2.1: benzene / 15 h / 20 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / toluene / -78 - 0 °C / Inert atmosphere

3.2: 1 h / 20 °C / Inert atmosphere

4.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 1 h / 20 °C / Inert atmosphere

With diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; toluene; benzene;
DOI:10.1021/jo202553a

Reference yield:

: 1360054-34-7
(E)-ethyl 5-(5-bromo-2-hydroxyphenyl)pent-2-enoate

: 1360054-11-0
(E)-5-(5-bromo-2-hydroxyphenyl)pent-2-enyl 2,2,2-trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / toluene / -78 - 0 °C / Inert atmosphere

1.2: 1 h / 20 °C / Inert atmosphere

2.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 1 h / 20 °C / Inert atmosphere

With diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; toluene;
DOI:10.1021/jo202553a