1,3-Dichloroadamantane

Base Information

• Chemical Name: 1,3-Dichloroadamantane
• CAS No.: 16104-50-0
• Molecular Formula: C10H14Cl2
• Molecular Weight: 205.127
• Mol file: 16104-50-0.mol

Synonyms:Adamantane,1,3-dichloro- (7CI,8CI);

Chemical Property of 1,3-Dichloroadamantane

Chemical Property:

• Vapor Pressure: 0.00815mmHg at 25°C
• Melting Point: 130-131 °C
• Refractive Index: 1.549
• Boiling Point: 276.3 °C at 760 mmHg
• Flash Point: 118.8 °C
• PSA: 0.00000
• Density: 1.25 g/cm³
• LogP: 3.55540
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

1,3-Dichloroadamantane 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Dichloroadamantane

There total 27 articles about 1,3-Dichloroadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

adamantane (281-23-2) → 1,3-dichloroadamantane (16104-50-0)

Guidance literature:

With Iodine monochloride; In tetrachloromethane; for 5h; Heating;

DOI:10.1016/S0040-4039(00)84269-0

Reference yield: 92.0%

N,N-dichloro-adamantan-1-amine (24375-05-1) → 1-chloroadamantane (935-56-8) + 1,3-dichloroadamantane (16104-50-0)

Guidance literature:

In dichloromethane; at 250 ℃; various temperatures and concentrations; solution pyrolysis in decalin or o-dichlorobenzene; neat pyrolysis;

DOI:10.1021/jo01314a003

Reference yield: 90.5%

adamantane (281-23-2) → 1-chloroadamantane (935-56-8) + 2-chloroadamantane (7346-41-0) + 1,3-dichloroadamantane (16104-50-0)

Guidance literature:

With aluminium trichloride; tertiary butyl chloride; In tetrachloromethane; for 4h; Ambient temperature;

upstream raw materials:

adamantane

1-chloroadamantane

chloroamine-T

7-methylenebicyclo[3.3.1]nonan-3-one

Downstream raw materials:

adamantane

1-dimethylsilyladamantane

1-(trimethylsilyl)adamantane

1-adamantane