(Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

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Chemical Name:(Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol
CAS No.:124044-26-4
Molecular Formula:C₃₂H₄₂O₂S₂Si
Molecular Weight:550.902
Hs Code.:

Synonyms:(Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

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Chemical Property of (Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

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Technology Process of (Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

There total 10 articles about (Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 124044-25-3
2,2-Dimethyl-thiopropionic acid S-[(Z)-(R)-7-(tert-butyl-diphenyl-silanyloxymethyl)-6-hydroxy-3,3-dimethyl-10-trimethylsilanyl-dec-7-ene-4,9-diynyl] ester

: 629-19-6
Dipropyl disulfide

: 124044-26-4
(Z)-(R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; methanol; for 3h;
DOI:10.1021/ja00207a036

Reference yield: 70.0%

: 124044-25-3
2,2-Dimethyl-thiopropionic acid S-[(Z)-7-(tert-butyl-diphenyl-silanyloxymethyl)-6-hydroxy-3,3-dimethyl-10-trimethylsilanyl-dec-7-ene-4,9-diynyl] ester

: 629-19-6
Dipropyl disulfide

: 124044-26-4
(Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

Guidance literature:: With sodium hydride; In tetrahydrofuran; methanol; at 0 ℃; for 4h;

Reference yield:

: 124044-22-0
(1,1-dimethylethyl)<(2-bromo-2-pentene-5-trimethylsilyl-4-ynyl)oxy>diphenylsilane

: 124044-26-4
(Z)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8,8-dimethyl-10-propyldisulfanyl-dec-3-ene-1,6-diyn-5-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) tert-butyllithium / 1.) THF, Et₂O, pentane, -120 deg C, 2.) THF, Et₂O, pentane, from -120 to -40 deg C, 3 h

2: 1.) lithium diisopropylamide, anhydr. cesium(III) chloride / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 30 min

3: 70 percent / NaH / tetrahydrofuran; methanol / 4 h / 0 °C

With cerium(lll) chloride; tert.-butyl lithium; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran; methanol;