tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane

Base Information

• Chemical Name: tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane
• CAS No.: 124044-27-5
• Molecular Formula: C₂₉H₃₆OSSi
• Molecular Weight: 460.756
• Mol file: 124044-27-5.mol

Synonyms:tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane

Chemical Property of tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane

There total 12 articles about tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

3,5-Dinitro-benzoic acid (R)-1-[(Z)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-1-en-3-ynyl]-6-mercapto-4,4-dimethyl-hex-2-ynyl ester (124044-18-4) → tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane (124044-27-5)

Guidance literature:

With cyclohexa-1,4-diene; triethylamine; In dimethyl sulfoxide; at 25 ℃;

DOI:10.1021/ja00207a036

Reference yield:

3,5-Dinitro-benzoic acid 1-[(Z)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-1-en-3-ynyl]-6-mercapto-4,4-dimethyl-hex-2-ynyl ester (124044-18-4) → tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane (124044-27-5)

Guidance literature:

With cyclohexa-1,4-diene; triethylamine; In dimethyl sulfoxide; at 23 ℃; for 10h;

Reference yield:

methanol (67-56-1) + 3,5-Dinitro-benzoic acid 1-[(Z)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-1-en-3-ynyl]-6-mercapto-4,4-dimethyl-hex-2-ynyl ester (124044-18-4) → tert-Butyl-[3-(3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane (124044-27-5) + tert-Butyl-[3-(2-methoxy-3,3-dimethyl-tetrahydro-thiophen-2-yl)-benzyloxy]-diphenyl-silane

Guidance literature:

With triethylamine; In dimethyl sulfoxide; at 23 ℃; for 10h;

upstream raw materials:

methanol

3,5-Dinitro-benzoic acid 1-[(Z)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-1-en-3-ynyl]-6-mercapto-4,4-dimethyl-hex-2-ynyl ester

4-Methoxybenzenethiol

3,5-Dinitro-benzoic acid 1-[(Z)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-1-en-3-ynyl]-4,4-dimethyl-6-propyldisulfanyl-hex-2-ynyl ester