1,14-diazido-3,6,9,12-tetraoxatetradecane

Base Information

• Chemical Name: 1,14-diazido-3,6,9,12-tetraoxatetradecane
• CAS No.: 182760-73-2
• Molecular Formula: C₁₀H₂₀N₆O₄
• Molecular Weight: 288.307
• Mol file: 182760-73-2.mol

Synonyms:1,14-diazido-3,6,9,12-tetraoxatetradecane

Chemical Property of 1,14-diazido-3,6,9,12-tetraoxatetradecane

Chemical Property:

• Density: 1.129
• Storage Temp.: -20°C Freezer
• Solubility.: Chloroform

Purity/Quality:

97% ^*data from raw suppliers

1,14-Diazido-3,6,9,12-tetraoxatetradecane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Multifunctional alkylating agent. Multifunctional alkylating agent

Technology Process of 1,14-diazido-3,6,9,12-tetraoxatetradecane

There total 8 articles about 1,14-diazido-3,6,9,12-tetraoxatetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3,6,9,12-tetraoxatetradecane-1,14-diyl bis(4-methylbenzenesulfonate) → 1,14-diazido-3,6,9,12-tetraoxatetradecane (182760-73-2,82055-94-5)

Guidance literature:

With sodium azide; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; at 80 ℃; for 20h; Inert atmosphere;

DOI:10.3390/molecules180911639

Reference yield: 79.0%

penta(ethylene glycol) bis(p-toluenesulfonate) (41024-91-3) → 1,14-diazido-3,6,9,12-tetraoxatetradecane (182760-73-2,82055-94-5)

Guidance literature:

With sodium azide; In ethanol; for 48h; Reflux;

Reference yield: 77.0%

pentaethylene glycol dimesylate (109789-39-1) → 1,14-diazido-3,6,9,12-tetraoxatetradecane (182760-73-2,82055-94-5)

Guidance literature:

With sodium azide; In ethanol; for 8h; Reflux;

DOI:10.1021/acs.inorgchem.5b00748

upstream raw materials:

1,14-dichloro-3,6,9,12-tetraoxatetradecane

penta(ethylene glycol) bis(p-toluenesulfonate)

Pentaethylene glycol

pentaethylene glycol dimesylate

Downstream raw materials:

C₄₆H₅₄N₈O₇

C₄₆H₅₄N₈O₇

bis{4-(4-chlorophenyl)-1-[4-(4-fluorophenyl)-4-oxobutyl]piperidin-4-yl} 3,3’-[3,6,9,12-tetraoxatetradecane-1,14-diylbis(1H-1,2,3-triazole-1,4-diyl)]dipropanoate

1,14-diamino-3,6,9,12-tetraoxatetradecane