1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

Base Information

Chemical Name:1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol
CAS No.:705967-68-6
Molecular Formula:C₂₅H₂₃N₅O₅
Molecular Weight:473.488
Hs Code.:

1,5-anhydro-4,6-O-benzylidene-2-(N<sup>6</sup>-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

Synonyms:1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

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Chemical Property of 1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

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Technology Process of 1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

There total 3 articles about 1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 98-88-4
benzoyl chloride

: 705967-67-5
1,5-anhydro-4,6-O-benzylidene-2-deoxy-2-(adenin-9-yl)-D-altro-hexitol

: 705967-68-6
1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

Guidance literature:: 1,5-anhydro-4,6-O-benzylidene-2-deoxy-2-(adenin-9-yl)-D-altro-hexitol; With pyridine; chloro-trimethyl-silane; at 20 ℃; for 1h;

benzoyl chloride; at 20 ℃; for 2h;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 0.0833333h;
DOI:10.1081/NCN-120028338

Reference yield:

: 66224-66-6,66224-67-7,66224-68-8,66224-69-9,134434-48-3,134434-49-4,134454-76-5,134461-75-9
adenine

: 705967-68-6
1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium hydride; 12-crown-4 / dimethylformamide / 1.5 h / 120 °C

1.2: 80 percent / dimethylformamide / 1 h / 120 °C

2.1: trimethylsilyl chloride; pyridine / 1 h / 20 °C

2.2: 2 h / 20 °C

2.3: 79 percent / TBAF / tetrahydrofuran / 0.08 h / 20 °C

With pyridine; chloro-trimethyl-silane; (1,4,7,10-tetraoxacyclododecane); lithium hydride; In N,N-dimethyl-formamide;
DOI:10.1081/NCN-120028338

Reference yield:

: 92283-88-0
1,5:2,3-dianhydro-4,6-O-benzylidene-D-allitol

: 705967-68-6
1,5-anhydro-4,6-O-benzylidene-2-(N⁶-benzoyladenin-9-yl)-2-deoxy-D-altro-hexitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium hydride; 12-crown-4 / dimethylformamide / 1.5 h / 120 °C

1.2: 80 percent / dimethylformamide / 1 h / 120 °C

2.1: trimethylsilyl chloride; pyridine / 1 h / 20 °C

2.2: 2 h / 20 °C

2.3: 79 percent / TBAF / tetrahydrofuran / 0.08 h / 20 °C

With pyridine; chloro-trimethyl-silane; (1,4,7,10-tetraoxacyclododecane); lithium hydride; In N,N-dimethyl-formamide;
DOI:10.1081/NCN-120028338