(2R)-methyl 2-methyl-2-(trans-styryl)acetate

Base Information

Chemical Name:(2R)-methyl 2-methyl-2-(trans-styryl)acetate
CAS No.:182699-64-5
Molecular Formula:C₁₂H₁₄O₂
Molecular Weight:190.242
Hs Code.:

Synonyms:(2R)-methyl 2-methyl-2-(trans-styryl)acetate

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Chemical Property of (2R)-methyl 2-methyl-2-(trans-styryl)acetate

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Technology Process of (2R)-methyl 2-methyl-2-(trans-styryl)acetate

There total 5 articles about (2R)-methyl 2-methyl-2-(trans-styryl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 33599-85-8
(E)-2-methyl-4-phenyl-3-butenoic acid methyl ester

: 143317-48-0
(S,E)-2-methyl-4-phenyl-3-butenoic acid

: 182699-64-5
(2R)-methyl 2-methyl-2-(trans-styryl)acetate

Guidance literature:: With sodium azide; phosphate buffer; In water; at 25 ℃; for 120h; Yields of byproduct given; 2-propanol-treated Candida rugosa lipase presence, pH 7.0;
DOI:10.1021/jo960972i

Reference yield:

: 91083-82-8,24891-74-5,34541-74-7
(E)-methyl 4-phenylbut-3-enoate

: 182699-64-5
(2R)-methyl 2-methyl-2-(trans-styryl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) lithium diisopropylamide / 1.) THF, hexanes, -60 deg C, 10 min, 2.) THF, hexanes, 5 deg C, 15 min

2: phosphate buffer, sodium azide / H₂O / 120 h / 25 °C / 2-propanol-treated Candida rugosa lipase presence, pH 7.0

With sodium azide; phosphate buffer; lithium diisopropyl amide; In water;
DOI:10.1021/jo960972i

Reference yield:

: 16939-57-4
(E)-buta-1,3-dienylbenzene

: 182699-65-6
methyl (S,E)-2-methyl-4-phenylbut-3-enoate

: 182699-64-5
(2R)-methyl 2-methyl-2-(trans-styryl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: C₃₂H₂₇F₁₂NOPPd⁽¹⁺⁾*BF₄^(1-); triethylamine / dichloromethane / 15 h / 22 °C / Inert atmosphere

2: lithium carbonate; magnesium bis(monoperoxyphthalate)hexahydrate / 3 h / 0 °C / Inert atmosphere

With magnesium bis(monoperoxyphthalate)hexahydrate; C₃₂H₂₇F₁₂NOPPd⁽¹⁺⁾*BF₄^(1-); lithium carbonate; triethylamine; In dichloromethane;
DOI:10.1021/jacs.7b13300