(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

Base Information

Chemical Name:(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline
CAS No.:1225377-74-1
Molecular Formula:C₃₁H₄₄N₂Si₂
Molecular Weight:500.875
Hs Code.:

Synonyms:(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

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Chemical Property of (4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

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Technology Process of (4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

There total 12 articles about (4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: C₂₁H₂₆N₂

: 1225377-74-1
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

Guidance literature:: With dicarbonylcyclopentadienylcobalt; In tetrahydrofuran; at 140 ℃;
DOI:10.1016/j.bmcl.2014.05.060

Reference yield: 78.0%

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 1225377-71-8
2-((4aR,5R,7S,8aS)-1-benzyl-8a-ethynyl-7-methyldecahydroquinolin-5-yl)acetonitrile

: 1225377-76-3
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

: 1225377-74-1
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

Guidance literature:: With dicarbonylcyclopentadienylcobalt; In tetrahydrofuran; at 140 ℃; for 20h; regioselective reaction; Inert atmosphere; Sealed tube; Degassing;
DOI:10.1021/ja101956x

Reference yield: 70.0%

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 1225377-71-8
2-((4aR,5R,7S,8aS)-1-benzyl-8a-ethynyl-7-methyldecahydroquinolin-5-yl)acetonitrile

: 1225377-74-1
(4aR,5S,10bR,12R)-1-benzyl-12-methyl-9-(trimethylsilyl)-8-((trimethylsilyl)ethynyl)-2,3,4,4a,5,6-hexahydro-1H-5,10b-propano-1,7-phenanthroline

Guidance literature:: With dicarbonylcyclopentadienylcobalt; In chlorobenzene; at 131 ℃; for 8h; regioselective reaction; Inert atmosphere; Irradiation;
DOI:10.1021/jo400695c