5-Methoxy-2-methylpyridin-1-ium-1-olate

Base Information

• Chemical Name: 5-Methoxy-2-methylpyridin-1-ium-1-olate
• CAS No.: 35392-66-6
• Molecular Formula: C₇H₉NO₂
• Molecular Weight: 139.154
• Hs Code.: 2933399090
• DSSTox Substance ID: DTXSID60480748
• Wikidata: Q82315803
• Mol file: 35392-66-6.mol

Synonyms:35392-66-6;5-methoxy-2-methylpyridin-1-ium-1-olate;5-Methoxy-2-methylpyridine 1-oxide;5-methoxy-2-methyl-1-oxidopyridin-1-ium;SCHEMBL731371;5-Methoxy-2-picoline N-oxide;DTXSID60480748;HAMUUCVAFXJSLN-UHFFFAOYSA-N;5-Methoxy-2-methylpyridine1-oxide;2-Methyl-5-methoxypyridine-n-oxide;5-methoxy-2-methylpyridine-N-oxide;6-methyl-3-methoxypyridine N-oxide;5-Methoxy-2-methylpyridine-1-oxide;2-methyl-5-methoxy-pyridine-N-oxide;5-Methoxy-2-methyl-pyridine 1-oxide;AKOS006316129;CS-0234047;5-Methoxy-2-methyl-1-oxo-1lambda~5~-pyridine;EN300-138256

Chemical Property of 5-Methoxy-2-methylpyridin-1-ium-1-olate

Chemical Property:

• Boiling Point: 320.8±22.0 °C(Predicted)
• PSA: 34.69000
• Density: 1.07±0.1 g/cm3(Predicted)
• LogP: 1.43210
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 139.063328530
• Heavy Atom Count: 10
• Complexity: 108

Purity/Quality:

99% ^*data from raw suppliers

5-methoxy-2-methylpyridin-1-ium-1-olate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=[N+](C=C(C=C1)OC)[O-]

Technology Process of 5-Methoxy-2-methylpyridin-1-ium-1-olate

There total 5 articles about 5-Methoxy-2-methylpyridin-1-ium-1-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

5-methoxy-2-picoline (55270-47-8) → 5-methoxy-2-methylpyridine-1-oxide (35392-66-6)

Guidance literature:

5-methoxy-2-picoline; With dihydrogen peroxide; methyltrioxorhenium(VII); In chloroform; water; at 20 ℃;

With manganese(IV) oxide; In chloroform; water; at 20 ℃;

Reference yield: 72.0%

5-methoxy-2-picoline (55270-47-8) + m-chloroperoxybenzoic acid (64741-01-1) + sodium sulfate (7757-82-6) → 5-methoxy-2-methylpyridine-1-oxide (35392-66-6)

Guidance literature:

In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate;

Reference yield:

5-methoxy-2-picoline (55270-47-8) → 5-methoxy-2-methylpyridine-1-oxide (35392-66-6) + 2-acetoxymethyl-5-methoxypyridine (75342-32-4)

Guidance literature:

With manganese dioxide; dihydrogen peroxide; In water; acetic acid;

upstream raw materials:

5-methoxy-2-picoline

5-Hydroxy-2-methylpyridine

dihydrogen peroxide

m-chloroperoxybenzoic acid

Downstream raw materials:

3-methoxy-2-methyl-6-nitropyridine 1-oxide

5-methoxy-2-methyl-4-nitro-pyridine-1-oxide

2-hydroxymethyl-5-methoxypyridine

5-methoxy-2-pyridinecarboxaldehyde