2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

Base Information

Chemical Name:2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine
CAS No.:795311-33-0
Molecular Formula:C₂₂H₂₂N₂O₃Si
Molecular Weight:390.514
Hs Code.:

Synonyms:2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

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Chemical Property of 2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

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Technology Process of 2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

There total 3 articles about 2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 586-78-7
para-nitrophenyl bromide

: 795311-52-3
(E)-β-(2-pyridyldimethylsilyl)-4-methoxystyrene

: 795311-33-0
2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

Guidance literature:: With tri-tert-butyl phosphine; triethylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In 1,4-dioxane; at 80 ℃;
DOI:10.1021/ol048620i

Reference yield:

: 696-62-8
para-iodoanisole

: 795311-33-0
2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / tri(2-furyl)phosphine; Et₃N / Pd₂(dba)3*CHCl₃ / tetrahydrofuran / 50 °C

2: 39 percent / P(t-Bu)3; Et₃N / Pd₂(dba)3*CHCl₃ / dioxane / 80 °C

With trifuran-2-yl-phosphane; tri-tert-butyl phosphine; triethylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; 1,4-dioxane; 1: Mizoroki-Heck reaction / 2: Mizoroki-Heck reaction;
DOI:10.1021/ol048620i

Reference yield:

: 321155-39-9
dimethyl(2-pyridinyl)(vinyl)silane

: 795311-33-0
2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / tri(2-furyl)phosphine; Et₃N / Pd₂(dba)3*CHCl₃ / tetrahydrofuran / 50 °C

2: 39 percent / P(t-Bu)3; Et₃N / Pd₂(dba)3*CHCl₃ / dioxane / 80 °C

With trifuran-2-yl-phosphane; tri-tert-butyl phosphine; triethylamine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; 1,4-dioxane; 1: Mizoroki-Heck reaction / 2: Mizoroki-Heck reaction;
DOI:10.1021/ol048620i