(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

Base Information

Chemical Name:(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane
CAS No.:1623063-21-7
Molecular Formula:C₂₅H₃₅NO₇
Molecular Weight:461.555
Hs Code.:

Synonyms:(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

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Chemical Property of (3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

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Technology Process of (3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

There total 7 articles about (3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1623063-20-6
(2R,3R,4S)-4-[(2S,3R)-2-benzamido-3-hydroxybutanoyloxy]-2-butyl-3-(3-methylbutanoyloxy)pentanoic acid

: 1623063-21-7
(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

Guidance literature:: With 2-methyl-6-nitrobenzoic anhydride; 4-(dimethylamino)pyridine N-oxide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 72h;
DOI:10.1002/ejoc.201402430

Reference yield:

: 1623063-29-5
C₃₁H₄₇NO₇

: 1623063-21-7
(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

Guidance literature:: Multi-step reaction with 4 steps

1.1: camphor-10-sulfonic acid / methanol / 12 h / 0 - 20 °C

2.1: sodium periodate; cerium(III) chloride heptahydrate; ruthenium trichloride / water; acetonitrile; ethyl acetate / 0.08 h / 0 - 35 °C

2.2: 12 h / 0 °C

3.1: sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 4 h / 0 °C

4.1: 2-methyl-6-nitrobenzoic anhydride; 4-(dimethylamino)pyridine N-oxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 72 h / 20 °C

With ruthenium trichloride; sodium chlorite; sodium periodate; sodium dihydrogenphosphate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; 2-methyl-6-nitrobenzoic anhydride; 4-(dimethylamino)pyridine N-oxide; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane; water; ethyl acetate; acetonitrile; tert-butyl alcohol;
DOI:10.1002/ejoc.201402430

Reference yield:

: 1623063-16-0
(2R,3R,4S)-4-butyl-2-(4-methoxybenzyloxy)hexa-5-en-3-yl 3-methylbutanoate

: 1623063-21-7
(3S,4R,7R,8R,9S)-3-benzamido-7-butyl-4,9-dimethyl-8-(3-methylbutanoyloxy)-2,6-dioxo-1,5-dioxacyclononane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 1 h / 0 °C

2.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 12 h / 0 - 20 °C

3.1: camphor-10-sulfonic acid / methanol / 12 h / 0 - 20 °C

4.1: sodium periodate; cerium(III) chloride heptahydrate; ruthenium trichloride / water; acetonitrile; ethyl acetate / 0.08 h / 0 - 35 °C

4.2: 12 h / 0 °C

5.1: sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 4 h / 0 °C

6.1: 2-methyl-6-nitrobenzoic anhydride; 4-(dimethylamino)pyridine N-oxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 72 h / 20 °C

With ruthenium trichloride; sodium chlorite; sodium periodate; sodium dihydrogenphosphate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; 2-methyl-6-nitrobenzoic anhydride; 4-(dimethylamino)pyridine N-oxide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; toluene; acetonitrile; tert-butyl alcohol;
DOI:10.1002/ejoc.201402430