C₅H₅(CO)2MnSC₆H₄NO₂

Base Information

Chemical Name:C₅H₅(CO)2MnSC₆H₄NO₂
CAS No.:136378-96-6
Molecular Formula:C₁₃H₉MnNO₄S
Molecular Weight:330.223
Hs Code.:

C<sub>5</sub>H<sub>5</sub>(CO)2MnSC<sub>6</sub>H<sub>4</sub>NO<sub>2</sub>

Synonyms:C₅H₅(CO)2MnSC₆H₄NO₂

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Chemical Property of C₅H₅(CO)2MnSC₆H₄NO₂

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Technology Process of C₅H₅(CO)2MnSC₆H₄NO₂

There total 1 articles about C₅H₅(CO)2MnSC₆H₄NO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 12079-65-1
cymantrene

: 100-32-3
di(p-nitrophenyl) disulfide

: 136378-96-6
C₅H₅(CO)2MnSC₆H₄NO₂

Guidance literature:: In tetrahydrofuran; byproducts: ((C5H5)(CO)2Mn)2S; Irradiation (UV/VIS); carried out with exclusion of air and moisture; complex dissolved in THF and irradiated for 3-4 h at 10°C, addn. of disulfide, mixt. stirred for 8 h at room temp., air passed through the soln. for 1 min.; column chromy.(silica gel, 1. n-pentane; 2. n-pentane-CH2Cl2 (10:1); 3. pentane-Et2O (4:1)), crystn. from n-pentane-CH2Cl2 (3:2) at -30°C; elem. anal.;

Reference yield: 42.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 136378-96-6
C₅H₅(CO)2MnSC₆H₄NO₂

: 12079-65-1
cymantrene

: 136379-20-9
{C₅H₅(CO)2Mn}2SC₆H₄NO₂⁽¹⁺⁾*PF₆^(1-)*0.5CH₂Cl₂ = {C₅H₅(CO)2Mn}2SC₆H₄NO₂PF₆*0.5CH₂Cl₂

Guidance literature:: In toluene; carried out with exclusion of air and moisture; 1 equiv of AgPF6 added to a stirred soln. of the Pd complex; mixt. stirred for further 20 min. at room temp.; volume reduced in vac., pentane added, filtered through silanized silica gel, elution with CH2Cl2, crystn. from CH2Cl2-Et2O (1:1) at -30°C; elem. anal.;