Technology Process of C21H34O4SSi
There total 9 articles about C21H34O4SSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogenchloride;
In
tetrahydrofuran;
at 20 ℃;
for 0.666667h;
DOI:10.1021/ja071217x
- Guidance literature:
-
Multi-step reaction with 7 steps
1: urea*H2O2; Na2CO3; (CF3CO)2O / CH2Cl2 / 1.5 h / 0 °C
2: 90 percent / toluene / 3 h / 65 °C
3: diethyl ether / 20 °C
4: oxalyl chloride; DMSO; Et3N / CH2Cl2 / 2 h / -70 - 20 °C
5: 50 mg / diisobutylaluminum hydride / CH2Cl2 / 1 h / -72 °C
6: 2,6-lutidine / CH2Cl2 / 1 h / 20 °C
7: 86 mg / aq. HCl / tetrahydrofuran / 0.67 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; oxalyl dichloride; urea hydrogen peroxide adduct; diisobutylaluminium hydride; sodium carbonate; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride;
In
tetrahydrofuran; diethyl ether; dichloromethane; toluene;
4: Swern oxidation;
DOI:10.1021/ja071217x
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 90 percent / toluene / 3 h / 65 °C
2: diethyl ether / 20 °C
3: oxalyl chloride; DMSO; Et3N / CH2Cl2 / 2 h / -70 - 20 °C
4: 50 mg / diisobutylaluminum hydride / CH2Cl2 / 1 h / -72 °C
5: 2,6-lutidine / CH2Cl2 / 1 h / 20 °C
6: 86 mg / aq. HCl / tetrahydrofuran / 0.67 h / 20 °C
With
2,6-dimethylpyridine; hydrogenchloride; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; diethyl ether; dichloromethane; toluene;
3: Swern oxidation;
DOI:10.1021/ja071217x
