4-methyl-4-<2-allyl>-2-cyclohexen-1-one

Base Information

Chemical Name:4-methyl-4-<2-allyl>-2-cyclohexen-1-one
CAS No.:87603-69-8
Molecular Formula:C₁₄H₂₄OSi
Molecular Weight:236.429
Hs Code.:

4-methyl-4-<2-<trimethylsilyl)methyl>allyl>-2-cyclohexen-1-one

Synonyms:4-methyl-4-<2-allyl>-2-cyclohexen-1-one

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Chemical Property of 4-methyl-4-<2-allyl>-2-cyclohexen-1-one

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Technology Process of 4-methyl-4-<2-allyl>-2-cyclohexen-1-one

There total 4 articles about 4-methyl-4-<2-allyl>-2-cyclohexen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100812-96-2
3-ethoxy-6-methyl-6-<2-<(-trimethylsilyl)methyl>allyl>-2-cyclohexen-1-one

: 87603-69-8
4-methyl-4-<2-allyl>-2-cyclohexen-1-one

Guidance literature:: With lithium aluminium tetrahydride; oxonium; Yield given. Multistep reaction;
DOI:10.1016/S0040-4039(00)81804-3

Reference yield:

: 62952-33-4
3-ethoxy-6-methylcyclohex-2-en-1-one

: 87603-69-8
4-methyl-4-<2-allyl>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) LDA, hexamethylphosphoramide (HMPA) / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, from -78 deg C to RT, 5 h

2: lithium aluminium hydride / tetrahydrofuran / 2 h / 0 °C

3: 1 N aq. HCl / tetrahydrofuran / 0.5 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/jo00360a022

Reference yield:

: 80121-73-9
2-(trimethylsilyl)methylallyl iodide

: 87603-69-8
4-methyl-4-<2-allyl>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) LDA, hexamethylphosphoramide (HMPA) / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, from -78 deg C to RT, 5 h

2: lithium aluminium hydride / tetrahydrofuran / 2 h / 0 °C

3: 1 N aq. HCl / tetrahydrofuran / 0.5 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/jo00360a022