2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaazido-

Base Information

• Chemical Name: 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaazido-
• CAS No.: 22295-99-4
• Molecular Formula: N21P3
• Molecular Weight: 387.062
• Mol file: 22295-99-4.mol

Synonyms:1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexaazido-2,2,4,4,6,6-hexahydro- (8CI,9CI)

Chemical Property of 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaazido-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: A violent explosive sensitive to shock or friction. Very unstable. Upon decompositi"> x and POx. See also AZIDES." target="_blank">A violent explosive sensitive to shock or friction. Very unstable. Upon decompositi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaazido-

There total 5 articles about 2l5,4l5,6l5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaazido- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium azide (19597-69-4,157302-05-1) + trichloro(o-phenylenedioxy)phosphorane (2007-97-8) → 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) + hexaazido cyclotriphosphazene (22295-99-4) + octachlorocyclotetraphosphazene (2950-45-0)

Guidance literature:

In nitrobenzene; not isolated, detected by NMR;

DOI:10.1039/DT9810002292

Reference yield:

sodium azide + 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) → hexaazido cyclotriphosphazene (22295-99-4)

Guidance literature:

In acetone; addn. of activated NaN3 in 8 ml H2O to (PNCl2)3 in 6 ml acetone; short heating at 45°C; storing for 2 h;; addn. of 20 ml H2O; extraction with ether;;

Reference yield:

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine (940-71-6,16422-79-0) + trimethylsilylazide (4648-54-8) → hexaazido cyclotriphosphazene (22295-99-4)

Guidance literature:

In further solvent(s); P3N3Cl6 added to Schlenk flask under Ar; dissolved in propionitrile at room temp.; (CH3)3SiN3 added dropwise to stirred soln. under N2 purge; stream of N2 passed; soln. warmed to 60°C; stirred 3 h; the stirredfor 19 h at room temp.; react, mixt. concd. (30°C, 50 mbar); dried in vac.; purified by sublimation (0.001 mbar, 130°C oil bath, -86°C cold finger;

DOI:10.1002/anie.200601670

upstream raw materials:

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

lithium azide

trichloro(o-phenylenedioxy)phosphorane

trimethylsilylazide

Refernces

• 1、 Muralidharan,Omotowa, Bamidele A.,Twamley, Brendan,Piekarski, Crystal,Shreeve, Jean'ne M.. "High energy density materials from azido cyclophosphazenes". . p. 5193 - 5195. Retrieved 2005.