ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

Base Information

Chemical Name:ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane
CAS No.:65098-10-4
Molecular Formula:C₂₈H₂₉ClP₂Pt
Molecular Weight:658.019
Hs Code.:

Synonyms:ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

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Chemical Property of ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

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Technology Process of ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

There total 1 articles about ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 65098-10-4
ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

Guidance literature:: With hydrogenchloride; In diethyl ether; dichloromethane; dropwise addn. of HCl (in Et2O) to Pt-complex soln. (in CH2Cl2) at 0°C, stirring (15 min); evapn. to dryness, recrystn. (CH2Cl2/petroleum ether); elem. anal.;
DOI:10.1016/S0020-1693(00)93888-X

Reference yield: 77.0%

: 65098-10-4
ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

: 124-41-4
sodium methylate

: 102781-77-1
((C₆H₅)2PCH₂CH₂P(C₆H₅)2)PtC₂H₅(OCH₃)

Guidance literature:: In methanol; benzene; to suspn. (DPPE)PtEtCl in benzene soln. NaOCH3 in methanol added and soln. stirred overnight at 25°C; soln. stripped to dryness, solid extd. with THF, ext. stripped to dryness, solid recrystd. from warm toluene/pentane; elem. anal.;
DOI:10.1021/ja00276a018

Reference yield: 68.0%

: 65098-10-4
ethylplatinum chloro 1,2-bis(diphenylphosphino)ethane

: 1732-66-7
dimesityl phosphine

: 2923-28-6
silver trifluoromethanesulfonate

: 287945-21-5
Pt(P(C₆H₅)2C₂H₄P(C₆H₅)2)(CH₃CH₂)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pt(P(C₆H₅)2C₂H₄P(C₆H₅)2)CH₃CH₂PH(C₆H₂(CH₃)3)2(CF₃SO₃)

Guidance literature:: In tetrahydrofuran; byproducts: AgCl; PHMes2 and AgOTf were added to a stirred suspn. of complex in THF, stirred for 2 h at 20°C under N2; filtered, the solvent was removed in vac., ppt. was dissolved in THF, Et2O was added, cooled to -30°C; elem. anal.;
DOI:10.1021/om000164o