ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate

Base Information

• Chemical Name: ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate
• CAS No.: 927403-44-9
• Molecular Formula: C₆₀H₅₉N₄O₂Rh
• Molecular Weight: 971.06
• Mol file: 927403-44-9.mol

Synonyms:ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate

Chemical Property of ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate

There total 2 articles about ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

diazoacetic acid ethyl ester (623-73-4) + 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) → ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate (927403-44-9)

Guidance literature:

In benzene; ethyl diazoacetate was added to soln. Rh complex in benzene and stirred for 30 min under N2 atm. in absence of light; chromy. on silica (hexane-CH2Cl2 2:1 to 1:1); elem. anal.; Kinetics;

DOI:10.1021/om060833j

Reference yield: 68.0%

diazoacetic acid ethyl ester (623-73-4) + (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5) → ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate (927403-44-9)

Guidance literature:

In benzene; under N2 atm. ethyl diazoacetate was added to soln. Rh complex in benzene and stirred at room temp. in absence light for 15 min; chromy. on silica (hexane-CH2Cl2 2:1 to 1:1);

DOI:10.1021/om060833j

upstream raw materials:

diazoacetic acid ethyl ester

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride