(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

Base Information

Chemical Name:(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal
CAS No.:344796-28-7
Molecular Formula:C₂₀H₃₄O₄Si
Molecular Weight:366.573
Hs Code.:

Synonyms:(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

Suppliers and Price of (2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

There total 1 articles about (2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 344796-30-1
tert-Butyl-{(1S,2S)-1-[(S)-1-(4-methoxy-benzyloxy)-ethyl]-2-methyl-but-3-enyloxy}-dimethyl-silane

: 344796-28-7
(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

: (3R,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-5-(4-methoxy-benzyloxy)-3-methyl-hexan-2-one

Guidance literature:: With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; In 1,4-dioxane; water; tert-butyl alcohol; at 25 ℃; for 2h;
DOI:10.1021/ol0100273

Reference yield: 71.0%

: 99493-12-6
B-crotyldiisopinocampheylborane

: 344796-28-7
(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

: 344796-32-3
(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

: 344796-33-4
(3S,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

Guidance literature:: B-crotyldiisopinocampheylborane; (2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal; With boron trifluoride diethyl etherate; In tetrahydrofuran; diethyl ether; hexane; at -78 ℃; for 3h;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; diethyl ether; water; at 40 ℃; for 12h; Further stages.;
DOI:10.1021/ol0100273