4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

Base Information

Chemical Name:4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate
CAS No.:159351-38-9
Molecular Formula:C₁₇H₂₆O₃Si
Molecular Weight:306.477
Hs Code.:

Synonyms:4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

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Chemical Property of 4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

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Technology Process of 4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

There total 1 articles about 4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 95592-67-9
4-pivaloyloxybenzaldehyde

: 58207-97-9
tributyl[(E)-2-trimethylsilylethenyl]stannane

: 159351-38-9
4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 3h;
DOI:10.1016/S0040-4020(01)80702-X

Reference yield: 45.0%

: 159351-38-9
4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

: 147622-52-4
2,2-Dimethyl-propionic acid 4-[(R)-hydroxy-((2R,3R)-3-trimethylsilanyl-oxiranyl)-methyl]-phenyl ester

: 4-(E-(1S)-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

: 2,2-Dimethyl-propionic acid 4-[(S)-hydroxy-((2S,3S)-3-trimethylsilanyl-oxiranyl)-methyl]-phenyl ester

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; (-)-diisopropyl tartrate; In dichloromethane; toluene; at -20 ℃; for 13.5h; Yield given. Title compound not separated from byproducts;
DOI:10.1016/S0040-4020(01)80702-X

Reference yield:

: 159351-38-9
4-(E-1-hydroxy-3-trimethylsilylprop-2-enyl)phenyl-2,2-dimethylpropanoate

: (1S,2R,3R)-4-<1-(3,5-dimethoxy-2,6-diiodophenoxy)-2,3-epoxy-3-trimethylsilylpropanyl>phenyl 2,2-dimethylpropanoate

Guidance literature:: Multi-step reaction with 2 steps

2: 59 percent / diisopropyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / Ambient temperature

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran;
DOI:10.1016/S0040-4020(01)80702-X