Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane

Base Information

Chemical Name:Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane
CAS No.:58207-97-9
Molecular Formula:C17H38SiSn
Molecular Weight:389.284
Hs Code.:
Mol file:58207-97-9.mol

Synonyms:(E)-1-(tri-n-butylstannyl)-2-(trimethylsilyl)ethylene;(E)-1-(tributylstannyl)-2-(trimethylsilyl)ethene;1-(2-(trimethylsilyl)vinyl)tri-n-butylstannane;(E)-1-(trimethylsilyl)-2-(tri-n-butylstannyl)ethylene;

Suppliers and Price of Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane

Chemical Property:

PSA：0.00000
LogP:6.80830
Solubility.:sol ethers, DMF, hydrocarbon, aromatic solvents.

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Physical properties bp 96–102 °C/0.5 mmHg.
Uses (E)-1-Tri-n-butylstannyl-2- trimethylsilylethylene can be used in the Pd0-catalyzed cross coupling of vinyl and aryl halides or triflates;1,2 a source of β-trimethylsilylvinyllithium.

Technology Process of Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane

There total 7 articles about Tributyl[(1E)-2-(trimethylsilyl)ethenyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 688-73-3
tri-n-butyl-tin hydride

: 1066-54-2
trimethylsilylacetylene

: 58207-97-9,72178-98-4,141262-50-2
(2-trimethylsilylethenyl)tributylstannane

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In not given; 80°C, 24 h; isomer mixt. (E:Z=9:1) not sepd.;
DOI:10.1002/anie.199712891

Reference yield: 97.0%

: 4226-01-1
tri-n-butyltin lithium

: 917-54-4
methyllithium

: copper(l) cyanide

: 1066-54-2
trimethylsilylacetylene

: 58207-97-9
tributyl[(E)-2-trimethylsilylethenyl]stannane

Guidance literature:: In tetrahydrofuran; hexane; a soln. of stannyllithium in THF and MeLi in hexane and CuCN is stirred at -78°C for 30 min, dropwise addn. of acetylene-compd. in THF, the mixt. is stirred for 30 min (under nitrogen); the mixt. is warmed to 0°C during 1 h, and saturated aq. NH4Cl is added, extn. with Et2O, drying (MgSO4) and chromy., elem. anal.;