trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

Base Information

Chemical Name:trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate
CAS No.:86765-88-0
Molecular Formula:C₂₆H₃₀Cl₂N₂P₂Re*F₆P
Molecular Weight:834.562
Hs Code.:

trans,cis-dichloro(2,2'-bipyridyl)(PMe<sub>2</sub>Ph)2rhenium(III) hexafluorophosphate

Synonyms:trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

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Chemical Property of trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

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Technology Process of trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

There total 3 articles about trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: ammonium hexafluorophosphate

: 17099-98-8
(2,2'-bipyridine)ReCl₄

: 672-66-2
Dimethyl(phenyl)phosphine

: 86765-88-0
trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

Guidance literature:: In 2-methoxy-ethanol; mixt. of Re-complex and ligand was heated at reflux in 2-methoxyethanolfor 4 h under N2 with stirring, aq. NH4PF6 added; chromd. (toluene-CH3CN, alumina), recrystd. from toluene-CH3CN; elem. anal.;

Reference yield: 90.0%

: 366-18-7
[2,2]bipyridinyl

: ammonium hexafluorophosphate

: 14710-16-8,15613-32-8,24627-46-1
mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

: 86765-88-0
trans,cis-dichloro(2,2'-bipyridyl)(PMe₂Ph)2rhenium(III) hexafluorophosphate

Guidance literature:: In ethanol; byproducts: P(CH3)2(C6H5); to deoxygenated abs. EtOH Re-complex and ligand were added, refluxed for 20 h under N2 with stirring, cooled, soln. of NH4PF6 was added; concd., filtered, washed with water and ether, air dried, chromd. (alumina, toluene-CH3CN); elem. anal.;