Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III)

Base Information

• Chemical Name: Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III)
• CAS No.: 14710-16-8
• Molecular Formula: C₂₄H₃₃Cl₃P₃Re
• Molecular Weight: 707.013
• NSC Number: 168790
• Mol file: 14710-16-8.mol

Synonyms:Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III);14710-16-8;dimethyl(phenyl)phosphanium;trichlororhenium;NSC168790;NSC 168790;NSC-168790

Chemical Property of Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III)

Chemical Property:

• Melting Point: 165 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 40.77000
• Density: g/cm³
• LogP: 7.42560
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 709.065297
• Heavy Atom Count: 31
• Complexity: 325

Purity/Quality:

99%min ^*data from raw suppliers

Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[PH+](C)C1=CC=CC=C1.C[PH+](C)C1=CC=CC=C1.C[PH+](C)C1=CC=CC=C1.Cl[Re](Cl)Cl
• Uses: Reactant for synthesis of:Hydridobis(ethylene) and hydrido dinitrogen complexes of rheniumPolyhedral rhenaborane complexes

Technology Process of Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III)

There total 15 articles about Mer-Trichlorotris(dimethylphenylphosphine)rhenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + aluminium trichloride (7446-70-0) + mer-(PMe2Ph)3Cl2Re(3,4-NC4H2Me2) (227932-89-0) → mer-trichlorotris(dimethylphenylphosphine)rhenium(III) (14710-16-8,15613-32-8,24627-46-1)

Guidance literature:

In chloroform-d1; N2-atmosphere; excess of HCl, 1 equiv. of AlCl3, standing for 1-2 days; not sepd.; NMR-spectroscopy;

DOI:10.1021/om9900216

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + aluminium trichloride (7446-70-0) + (P((CH3)2C6H5))3Cl2Re(N-pyrrolyl) (227932-83-4) → mer-trichlorotris(dimethylphenylphosphine)rhenium(III) (14710-16-8,15613-32-8,24627-46-1)

Guidance literature:

DOI:10.1021/om9900216

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + aluminium trichloride (7446-70-0) + mer-(PMe2Ph)3Cl2Re(3-NC4H3Me)*H2O → mer-trichlorotris(dimethylphenylphosphine)rhenium(III) (14710-16-8,15613-32-8,24627-46-1)

Guidance literature:

DOI:10.1021/om9900216

upstream raw materials:

(P((CH₃)2C₆H₅))3Cl₂Re(N-pyrrolyl)

hydrogenchloride

aluminium trichloride

mer-(PMe₂Ph)3Cl₂Re(3,4-NC₄H₂Me₂)

Downstream raw materials:

ReH₃{PMe₂Ph}4

[Re(NCO)Cl₂(P(CH₃)2(C₆H₅))3]

[Re(NCO)3(P(CH₃)2(C₆H₅))3]

(η5-pentadienyl)tris(dimetylphenylphosphine)rhenium

Refernces

• 1、 He, Guomei,Chen, Jiangxi,Sung, Herman Ho-Yung,Williams, Ian Duncan,Jia, Guochen. "Substituent effect on reactions of ReH5(PMe2Ph)3 with propargyl alcohols". . . Retrieved 2021/02/09.
• 2、 Chen, Jiangxi,He, Guomei,Sung, Herman Ho-Yung,Williams, Ian Duncan,Lin, Zhenyang,Jia, Guochen. "Rhenium carbyne and η2-vinyl complexes from one-pot reactions of ReH5(PMe2Ph)3 with terminal alkynes". . p. 2693 - 2701. Retrieved 2010/08/06.