3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

Base Information

Chemical Name:3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde
CAS No.:853061-28-6
Molecular Formula:C₂₉H₃₄O₃Si
Molecular Weight:458.673
Hs Code.:

3-{2-[3-(<i>tert</i>-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

Synonyms:3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

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Chemical Property of 3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

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Technology Process of 3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

There total 10 articles about 3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 853061-26-4
3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propan-1-ol

: 853061-28-6
3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1139/v05-259

Reference yield:

: 853061-12-8
2-(3-hydroxy-propyl)-4-methoxy-benzaldehyde

: 853061-28-6
3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / imidazole / tetrahydrofuran / 0.75 h / 20 °C

2: 97 percent / sodium hydride / tetrahydrofuran / 0.33 h / 20 °C

3: 97 percent / diisobutylaluminium hydride / CH₂Cl₂ / 1 h / 0 °C

4: 93 percent / imidazole / tetrahydrofuran / 1.5 h / 20 °C

5: 98 percent / p-toluenesulfonate pyridinium salt / ethanol / 20 °C

6: 100 percent / DMSO; oxalyl chloride; triethylamine / CH₂Cl₂ / 3 h / 20 °C

With 1H-imidazole; oxalyl dichloride; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; ethanol; dichloromethane; 2: Horner-Emmons reaction / 6: Swern oxidation;
DOI:10.1139/v05-259

Reference yield:

: 853061-14-0
2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methoxy-benzaldehyde

: 853061-28-6
3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / sodium hydride / tetrahydrofuran / 0.33 h / 20 °C

2: 97 percent / diisobutylaluminium hydride / CH₂Cl₂ / 1 h / 0 °C

3: 93 percent / imidazole / tetrahydrofuran / 1.5 h / 20 °C

4: 98 percent / p-toluenesulfonate pyridinium salt / ethanol / 20 °C

5: 100 percent / DMSO; oxalyl chloride; triethylamine / CH₂Cl₂ / 3 h / 20 °C

With 1H-imidazole; oxalyl dichloride; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; ethanol; dichloromethane; 1: Horner-Emmons reaction / 5: Swern oxidation;
DOI:10.1139/v05-259