tris(neopentyl)tin bromide

Base Information

• Chemical Name: tris(neopentyl)tin bromide
• CAS No.: 60745-17-7
• Molecular Formula: C₁₅H₃₃BrSn
• Molecular Weight: 412.041
• Mol file: 60745-17-7.mol

Synonyms:tris(neopentyl)tin bromide

Chemical Property of tris(neopentyl)tin bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris(neopentyl)tin bromide

There total 1 articles about tris(neopentyl)tin bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trineopentyltin hydride (52741-72-7) + 6-Bromo-1-hexene (2695-47-8) → 1-hexene (592-41-6,25067-06-5) + methyl-cyclopentane (96-37-7) + tris(neopentyl)tin bromide (60745-17-7)

Guidance literature:

With 1-iodoundecane; In dodecane; Transferring of metal hydride, 6-bromo-1-hexene and solvent to react. tubes (flushed with argon and chilled in ice bath), degassing (freeze-thaw), sealing of tubes (vac., liq. N2), keeping in const.-temp. bath (273-338 K).; Quenching by immersion in liq. N2, addn. of 1-iodoundecane, detg. of abs. yields by GLC anal. of react. tubes with benzene as integration std., no redn. of 6-bromo-1-hexene obsd. after GLC anal. of a ref. tube not subjected to react. conditions.; Kinetics;

DOI:10.1021/om00100a021

Reference yield: 99.0%

2,2-dimethylpropylmagnesium chloride (13132-23-5) + tris(neopentyl)tin bromide (60745-17-7) → Tetra-neopentyl-zinn, Tetra-neopentylstannan (13356-21-3)

Guidance literature:

In benzene; 2h reflux in benzene;

Reference yield: 75.0%

3-phenyl-3-germatranylpropionic acid (106015-60-5) + tris(neopentyl)tin bromide (60745-17-7) → tris(neopentyl)-(3-phenyl-3-germatranyl)tin(IV) propionate (355018-25-6)

Guidance literature:

With Et₃N; In acetone; byproducts: Et3NHCl; under Ar, acetone soln. of 1 equiv. of Sn-compd. along with Et3N was added to acetone soln. of Ge-compd., reflux for 6 h; soln. was cooled, Et3NHCl was filtered off, solvent was removed in vac.,crystn. from petroleum ether:CHCl3(3:1), elem. anal.;

DOI:10.1081/SIM-100002047

upstream raw materials:

trineopentyltin hydride

6-Bromo-1-hexene

Downstream raw materials:

Tetra-neopentyl-zinn, Tetra-neopentylstannan

trineopentylphenylstannane

tris(neopentyl)-(3-phenyl-3-germatranyl)tin(IV) propionate

tris(neopentyl)-(3-(3-methoxyphenyl)-3-germatranyl)tin(IV) propionate