dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Chemical Name:dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:1198155-81-5
Molecular Formula:C₂₆H₄₁N₃O₇Si
Molecular Weight:535.713
Hs Code.:

Synonyms:dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Chemical Property of dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Technology Process of dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 1 articles about dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1198156-12-5
C₂₁H₃₅N₃O₅Si

: 123-76-2
levulinic acid

: 1198155-81-5
dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: C₂₁H₃₅N₃O₅Si; levulinic acid; With 2-chloro-1-methyl-pyridinium iodide; In dichloromethane; at 20 ℃; for 0.25h;

With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1021/ja907358k

Reference yield: 95.0%

: ethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-α/β-L-idopyranoside

: 1198155-81-5
dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

: dimethylthexylsilyl O-(2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-L-idopyranosyl)-(1->4)-O-2-azido-3-O-benzyl-6-O-levulinoyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: ethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-α/β-L-idopyranoside; dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃;
DOI:10.1021/ja907358k

Reference yield: 92.0%

: 1198155-81-5
dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

: 162681-47-2
ethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

: 1198156-17-0
dimethylthexylsilyl O-(2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->4)-O-2-azido-3-O-benzyl-6-O-levulinoyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: dimethylthexylsilyl 6-O-levulinoyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside; ethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃;
DOI:10.1021/ja907358k