5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide

Base Information

• Chemical Name: 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide
• CAS No.: 90522-16-0
• Molecular Formula: C₅₁H₃₃AlN₄O₂
• Molecular Weight: 760.83
• Mol file: 90522-16-0.mol

Synonyms:5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide

Chemical Property of 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide

There total 3 articles about 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6) + benzoic acid (65-85-0,8013-63-6) → 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide (90522-16-0)

Guidance literature:

In toluene; at 70 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.7b01050

Reference yield:

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + trimethylaluminum (75-24-1) + benzoic acid (65-85-0,8013-63-6) → 5,10,15,20-tetra(phenyl)porphyrinatoaluminum(III) hydroxide (90522-16-0)

Guidance literature:

In not given; benzoic acid added to soln. of Al(TPP)Me, generated by addn. of AlMe3 totetraphenylporphyrin; detd. by NMR;

DOI:10.1039/b605435h

Reference yield:

[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6) + benzoic acid (65-85-0,8013-63-6) → aluminum(III) porphyrin-OOCC6H5 (90522-16-0)

Guidance literature:

In dichloromethane; Al(III)OH-por and benzoic acid reacted in dichloromethane; NMR, MS;

DOI:10.1021/jp911937d

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

trimethylaluminum

benzoic acid

[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide