[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide

Base Information

• Chemical Name: [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide
• CAS No.: 60101-30-6
• Molecular Formula: C₄₄H₂₉AlN₄O
• Molecular Weight: 656.722
• Mol file: 60101-30-6.mol

Synonyms:[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide

Chemical Property of [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide

There total 3 articles about [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

aluminium trichloride (7446-70-0) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + phenol (108-95-2,27073-41-2) → [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6)

Guidance literature:

In further solvent(s); prepn. from meso-tetraphenylporphin and AlCl3 taken in 1:6 molar ratio in boiling PhOH (500 K) for 1 h; cooled; dissolved in CHCl3; washed (warm H2O); introduced into column with Al2O3; complex formed as red zone; isolated after repeated chromy.; distd. off (vac.); elem. anal.;

DOI:10.1007/s11504-008-2002-1

Reference yield:

(5,10,15,20-tetraphenylporphyrin)aluminum chloride (71102-37-9) → [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6)

Guidance literature:

With sodium hydroxide; In water; 8 h; removal of aq. phase, residue dried, chromd., elem. anal.;

DOI:10.1039/f19837900765

Reference yield:

aluminium trichloride (7446-70-0) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) → [5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6)

Guidance literature:

In carbon disulfide; addn. of AlCl3 to suspn. of TPP, stirring (dried atmosphere, ambient temp.); column chromy. (Al2O3), recrystn. (methanol);

DOI:10.1149/1.2095666

upstream raw materials:

aluminium trichloride

5,10,15,20-tetraphenyl-21H,23H-porphine

phenol

(5,10,15,20-tetraphenylporphyrin)aluminum chloride

Downstream raw materials:

[Al(OH)(C₄₄H₂₈N₄)]⁽¹⁺⁾

C₇₃H₅₃AlN₆O₆

[Al(TPP)(AqCOO)]

aluminum(III) porphyrin-OOCC₆H₅