[PhB(CH₂PPh₂)₃]FeCl

Base Information

Chemical Name:[PhB(CH₂PPh₂)₃]FeCl
CAS No.:494843-61-7
Molecular Formula:C₄₅H₄₁BClFeP₃
Molecular Weight:776.853
Hs Code.:

[PhB(CH<sub>2</sub>PPh<sub>2</sub>)<sub>3</sub>]FeCl

Synonyms:[PhB(CH₂PPh₂)₃]FeCl

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Chemical Property of [PhB(CH₂PPh₂)₃]FeCl

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Technology Process of [PhB(CH₂PPh₂)₃]FeCl

There total 2 articles about [PhB(CH₂PPh₂)₃]FeCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1665-00-5
dichloromethane-d2

: [(PhB(CH₂PPh₂)3)FeN(p-tolyl)]

: 494843-61-7
[PhB(CH₂PPh₂)₃]FeCl

Guidance literature:: With H₂; In dichloromethane-d2; byproducts: p-toluidine;
DOI:10.1021/ja0399122

Reference yield:

: 7647-01-0,15364-23-5
hydrogenchloride

: [[PhB(CH2PPh2)3Fe]2(μ-N)][Na(THF)5]

: 494843-61-7
[PhB(CH₂PPh₂)₃]FeCl

Guidance literature:: In tetrahydrofuran; byproducts: NH3, NaCl; under N2 atm.; Fe nitride complex was dissolved in THF in NMR tube; soln. was cooled to -35°C; 3 equiv. of HCl in Et2O/THF cooled to -35°C added; allowed to warm to room temp.; after 30 min volatiles were vac. transferred into soln. of HCl in Et2O; soln. stirred for 30 min at room temp.; volatiles removed (vac.); residue dissolved in DMSO-d6 or benzene-d6; monitored by NMR spectroscopy;
DOI:10.1021/ja0453073

Reference yield: 97.0%

: 16940-66-2
sodium tetrahydroborate

: 494843-61-7
[PhB(CH₂PPh₂)₃]FeCl

: [PhB(CH2PPh2)3]iron(II)(η4-H3BH)

Guidance literature:: In tetrahydrofuran; under N2; Fe complex reacted with NaBH4 (large excess) in THF at room temp.; stirred overnight; soln. filtered; volatiles removed under reduced pressure; taken up in benzene; crystd. by vapor diffusion of petroleum ether; elem. anal.;
DOI:10.1039/b509580h