ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

Base Information Edit

Chemical Name:ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate
CAS No.:82498-75-7
Molecular Formula:C₃₂H₄₄O₃Si
Molecular Weight:504.785
Hs Code.:
Mol file:82498-75-7.mol

Synonyms:ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

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Chemical Property of ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate Edit

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Technology Process of ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

There total 37 articles about ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 82493-54-7
ethyl 6(R)-hydroxy-2(E),4(E),8(Z)-tetradecatrienoate

: 58479-61-1
tert-butylchlorodiphenylsilane

: 82498-75-7
ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

Guidance literature:: In N,N-dimethyl-formamide; at 65 ℃; for 22h;
DOI:10.1021/jo00271a032

Reference yield: 65.0%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 100311-75-9
4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

: 82498-75-7
ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In acetonitrile; for 1h; Ambient temperature;
DOI:10.1016/S0040-4039(00)84936-9

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 82498-75-7
ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate

Guidance literature:: Multi-step reaction with 4 steps

1: 96 percent / imidazole / tetrahydrofuran / 8 h / 25 °C

2: 78 percent / trimethylsilyl iodide, propene / CHCl₃ / 0.5 h / 25 °C

3: 90 percent / benzene / 16 h / Heating

4: 1.) NaH / 1.) benzene, 25 deg C, 1 h, 2.) benzene, 0 deg C

With 1H-imidazole; propene; trimethylsilyl iodide; sodium hydride; In tetrahydrofuran; chloroform; benzene;
DOI:10.1021/jo00358a016