1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

Base Information

Chemical Name:1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride
CAS No.:1421868-58-7
Molecular Formula:C₅₄H₆₂O₉Si
Molecular Weight:883.166
Hs Code.:

Synonyms:1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

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Chemical Property of 1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

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Technology Process of 1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

There total 8 articles about 1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1421868-57-6
1-O-(tert-butyldiphenylsilyl)-2-O-(4-methoxybenzyl)-sn-glyceryl 2,3,4-tri-O-benzyl-6-O-acetyl-α-D-glucopyranoside

: 1421868-58-7
1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

Guidance literature:: With sodium methylate; In methanol; dichloromethane;
DOI:10.1021/jo302508e

Reference yield:

: 1421868-56-5
1,6-di-O-(tert-butyldiphenylsilyl)-2,5-di-O-(4-methoxybenzyl)-D-mannitol

: 1421868-58-7
1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

Guidance literature:: Multi-step reaction with 4 steps

1: sodium periodate / water; tetrahydrofuran / 3 h / 20 °C

2: sodium tetrahydroborate / water; ethanol / 2 h / 0 °C

3: tetra-(n-butyl)ammonium iodide; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 144 h / 20 °C / Molecular sieve; Inert atmosphere

4: sodium methylate / methanol; dichloromethane

With sodium tetrahydroborate; sodium periodate; sodium methylate; tetra-(n-butyl)ammonium iodide; 2,4,6-tri-tert-butylpyrimidine; In tetrahydrofuran; methanol; ethanol; dichloromethane; water;
DOI:10.1021/jo302508e

Reference yield:

: 866454-44-6
(2R)-3-[(tert-butyldiphenylsilyl)oxy]-2-(4-methoxybenzyloxy)propanal

: 1421868-58-7
1-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-3-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-sn-glyceride

Guidance literature:: Multi-step reaction with 3 steps

1: sodium tetrahydroborate / water; ethanol / 2 h / 0 °C

2: tetra-(n-butyl)ammonium iodide; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 144 h / 20 °C / Molecular sieve; Inert atmosphere

3: sodium methylate / methanol; dichloromethane

With sodium tetrahydroborate; sodium methylate; tetra-(n-butyl)ammonium iodide; 2,4,6-tri-tert-butylpyrimidine; In methanol; ethanol; dichloromethane; water;
DOI:10.1021/jo302508e